Anthropogenic factors such as leakages from fuel storage facilities contribute to the release of petroleum hydrocarbons into groundwater. Following the proliferation of fuel stations in residential areas, this research assessed physicochemical parameters, salinity, and levels of total petroleum hydrocarbons (TPH) in groundwater sources within selected residential areas. From the study, mean values of temperature (30.5 °C), pH (5.8), EC (181.5 μs/cm), TDS (90.7 mg/L), and salinity (0.1 ppm) were recorded. The highest mean concentration of TPH (9.5 mg/L) was recorded at location A, while three sampling points (J, L, and M) exhibited 0.0 mg/L. Notably, TPH concentrations exceeding permissible limits were observed at three sampling points (A, B, and R). Strong positive correlations were observed between EC and TDS (r = 0.9), as well as salinity and EC (r = 0.9) and TDS (r = 0.9). Matrix plots demonstrated non-linear relationships, except for TDS and EC, although TPH and temperature exhibited a slightly linear pattern. The distance from USTs to the groundwater sources varied in the area. At location H, this distance (25 m) was measured as the shortest, where the mean TPH concentration was 3.71 mg/L. However, site Q exhibited the longest distance of 535 m, accompanied by a mean TPH concentration of 1.1 mg/L. Though the proximity of USTs to groundwater sources exerted some level of influence on the groundwater system, multiple linear regression, ANOVA, and cluster analysis showed that this did not pose direct and major impacts on the concentrations of TPH. However, approaches are needed to remediate the affected groundwater sources.