Due to elevated temperatures and high vacuum levels in electron beam melting (EBM), spatter formation and accumulation in the feedstock powder, and sublimation of alloying elements from the base feedstock powder can affect the feedstock powder’s reusability and change the alloy composition of fabricated parts. This study focused on the experimental and thermodynamic analysis of spatter particles generated in EBM, and analyzed sublimating alloying elements from Alloy 718 during EBM. Heat shields obtained after processing Alloy 718 in an Arcam A2X plus machine were analyzed to evaluate the spatters and metal condensate. Comprehensive morphological, microstructural, and chemical analyses were performed using scanning electron microscopy (SEM), focused ion beam (FIB), and energy dispersive spectroscopy (EDS). The morphological analysis showed that the area coverage of heat shields by spatter increased from top (25%), indicating that the spatter particles had projectile trajectories. Similarly, the metal condensate had a higher thickness of ~50 μm toward the bottom of the heat shield, indicating more significant condensation of metal vapors at the bottom. Microstructural analysis of spatters highlighted that the surfaces of spatter particles sampled from the heat shields were also covered with condensate, and the thickness of the deposited condensate depended on the time of landing of spatter particles on the heat shield during the build. The chemical analysis showed that the spatter particles had 17-fold higher oxygen content than virgin powder used in the build. Analysis of the metalized layer indicated that it was formed by oxidized metal condensate and was significantly enriched with Cr due to its higher vapor pressure under EBM conditions.

High layer thicknesses for laser powder bed fusion are promising for productivity increase. However, these are associated with increased process instability, spatter generation and powder degradation, crucial for alloys sensitive to oxygen. The effect of increasing layer thickness from 30 to 60 µm is studied focusing on Ti-6Al-4V spatter formation during LPBF and its characterisation, with scanning and transmission electron microscopy, combustion analysis and X-ray photoelectron spectroscopy. Results indicate that spatters are covered with a uniform Ti-Al-based oxide layer and Al-rich oxide particulates, the thickness of which is about twice that present on virgin powder. The oxygen content was about 60% higher in spatters compared to the virgin powder. The study highlights that increasing the layer thickness to 60 µm permits to reduce the total generation of spatters by ∼40%, while maintaining similar spatter characteristics and static tensile properties. Hence, this allows to increase build rate without compromising process robustness.