Advances in the synthesis, growth, and characterization of complex transition metal oxides coupled with new experimental techniques in ultrafast optical spectroscopy have ushered in an exciting era of dynamics and control in these materials. Experiments utilizing femtosecond optical pulses can initiate and probe dynamics of the spin, lattice, orbital, and charge degrees of freedom. Major goals include (a) determining how interaction and competition between the relevant degrees of freedom determine macroscopic functionality in transition metal oxides (TMOs) and (b) searching for hidden phases in TMOs by controlling dynamic trajectories in a complex and pliable energy landscape. Advances in creating intense pulses from the far-IR spectrum through the visible spectrum enable mode-selective excitation to facilitate exploration of these possibilities. This review covers recent developments in this emerging field and presents examples that include the cuprates, manganites, and vanadates.

Dynamic polarization control of light is essential for numerous applications ranging from enhanced imaging to material characterization and identification. We present a reconfigurable terahertz metasurface quarter-wave plate consisting of electromechanically actuated microcantilever arrays. Our anisotropic metasurface enables tunable polarization conversion through cantilever actuation. Specifically, voltage-based actuation provides mode-selective control of the resonance frequency, enabling real-time tuning of the polarization state of the transmitted light. The polarization tunable metasurface has been fabricated using surface micromachining and characterized using terahertz time domain spectroscopy. We observe a $\sim 230\mathrm{GHz}$ cantilever actuated frequency shift of the resonance mode, sufficient to modulate the transmitted wave from pure circular polarization to linear polarization. Our CMOS-compatible tunable quarter-wave plate enriches the library of terahertz optical components, thereby facilitating practical applications of terahertz technologies.

Quantum materials are amenable to nonequilibrium manipulation with light, enabling modification and control of macroscopic properties. Light-based augmentation of superconductivity is particularly intriguing. Copper-oxide superconductors exhibit complex interplay between spin order, charge order, and superconductivity, offering the prospect of enhanced coherence by altering the balance between competing orders. We utilize terahertz time-domain spectroscopy to monitor the c-axis Josephson plasma resonance (JPR) in La _2−x Ba _x CuO ₄ (x = 0.115) as a direct probe of superconductivity dynamics following excitation with near-infrared pulses. Starting from the superconducting state, c-axis polarized excitation with a fluence of 100 μJ/cm ² results in an increase of the far-infrared spectral weight by more than an order of magnitude as evidenced by a blueshift of the JPR, interpreted as resulting from nonthermal collapse of the charge order. The photoinduced signal persists well beyond our measurement window of 300 ps and exhibits signatures of spatial inhomogeneity. The electrodynamic response of this metastable state is consistent with enhanced superconducting fluctuations. Our results reveal that La _2−x Ba _x CuO ₄ is highly sensitive to nonequilibrium excitation over a wide fluence range, providing an unambiguous example of photoinduced modification of order-parameter competition.