Lignin recovered from poplar, a key woody biomass resource proposed for lignocellulosic refineries, was investigated for conversion into carbon fibers. Aqueous solutions of ethanol at selected temperatures and compositions, where the requisite solvent and liquefied-lignin phases form, were used to purify and fractionate hybrid poplar (HP) lignin using the Aqueous Lignin Purification with Hot Agents (ALPHA) process. Sugars (<0.1%) and ash (0.01 ± 0.01%) content of the highest molecular weight fraction (Mw = 52 kDa) approached the limits of detection. This 52 kDa fraction could be dry spun with excellent stability and was subsequently converted into carbon fibers having strength (1.1 ± 0.2 GPa) and modulus (78 ± 8 GPa) essentially double those previously achieved with neat poplar and other hardwood lignins. Of equal importance, stabilization times were decreased by a factor of five. Such stabilization and strength/modulus improvements are essential for reducing the overall manufacturing cost of carbon fibers being proposed for cost-sensitive applications.

With shrinking size of electronic devices, increasing performance and accompanying heat dissipation, there is a need for efficient removal of this heat through packaging materials. Polymer materials are attractive packaging materials given their low density and electrical insulating properties, but they lack sufficient thermal conductivity that inhibits heat transfer rate. Hexagonal boron nitride (BN) possesses excellent thermal conductivity and is also electrically insulating, therefore BN-filled polymer composites were investigated in this study. Results showed successful continuous extrusion of BN-filled linear low-density polyethylene through micro-textured dies that is a scalable manufacturing process. Through-thickness thermal conductivity measurements established that 30 vol% BN content led to an over 500% increase in thermal conductivity over that of pure polymer. Textured film surface provided about a 50% increase in surface area when compared with non-textured films. This combination of increased surface area and enhanced thermal conductivity of BN-filled textured films indicates their potential application for improved convective thermal transport.

Corn stover-derived lignin, a sustainable and cheaper precursor, was ALPHA-fractionated and dry-spun using ethanol solvent to produce carbon fibers with improved properties via faster processing.