This article introduces an investigation on the sorption power of two polyacrylamide-based chelating sorbents for uranium ion removal from aqueous solutions. The studied sorption parameters involved pH, contact time, initial uranium concentration, and polymer dosage. The results revealed that a maximum uptake percentage of 65.3 mg/g and 20.1 mg/g for polymers I and II, respectively, could be obtained at pH 4 with 120 min shaking time. Based on isotherm, kinetic, and thermodynamic studies, the sorption process of uranium on the chelating polymers is said to follow Langmuir isotherm model with pseudo second-order mechanism and exothermic nature.
The sorption characteristics of uranium onto a strongly basic anion exchanger, Purolite A400, were investigated. The characteristics of Purolite A400, before and after sorption of uranium, were determined using scanning electron microscopy (SEM) and energetic-dispersive X-ray (EDX). The influence of the different parameters, which may affect the process of uranium sorption process, had been tracked. Specifically, impacts of initial uranium concentration, pH, contact time and temperature, on uranium removal, were studied. In addition, the sorption kinetics and equilibrium parameters were assessed. At the optimum conditions, the adsorption capacity of uranium was found to be nearly 117.6 mg/g. The kinetics and isotherm studies could show that the uranium sorption onto Purolite A400 is following the models of pseudo-second-order and Langmuir isotherm respectively. The thermodynamic parameters had indicated that the adsorption of uranium is an exothermic and spontaneous process. The detected results of uranium sorption could reveal that Purolite A400 is a suitable material for pre-concentration of uranium (VI) species from sulfate leach liquor.
16 September 2019 in Journal of Radioanalytical and Nuclear Chemistry
Carbonaceous materials produced from agricultural waste (palm kernel shell) by pyrolysis can be a proper type of low-cost adsorbent for wide uses in radioactive effluent treatment. In this context, the as-produced bio-char (labeled as PBC) and its sub-driven sulfuric acid and zinc oxide activated carbons (labeled as PBC-SA, and PBC-Zn respectively) were employed as adsorbents for uranium sorption from aqueous solution. Various analytical techniques, including SEM (Scanning Electron Microscopy), EXD (X-ray Diffraction), BET (Brunauer–Emmett–Teller), FTIR (Fourier Transform Infrared Spectroscopy), and Zeta potential, provide insights into the material characteristics. Kinetic and isotherm investigations illuminated that the sorption process using the three sorbents is nicely fitted with Pseudo-second-order-kinetic and Langmuir isotherm models. The picked data display that the equilibrium time was 60 min, and the maximum sorption capacity was 9.89, 16.8, and 21.9 mg/g for PBC, PBC-SA, and PBC-Zn respectively, which reflects the highest affinity for zinc oxide, activated bio-char, among the three adsorbents, for uranium taking out from radioactive wastewater. Sorption thermodynamics declare that the sorption of U(VI) is an exothermic, spontaneous, and feasible process. About 92% of the uranium-loaded PBC-Zn sorbent was eluted using 1.0 M CH3COONa sodium ethanoate solution, and the sorbent demonstrated proper stability for 5 consecutive sorption/desorption cycles.