For the National VI heavy-duty diesel vehicles, NO_x emission regulations are becoming more and more stringent, and the selective catalytic reduction (SCR) system has become a necessary device. The design of the adblue nozzle in the SCR system is especially critical, directly affecting the NO_x conversion efficiency and deposit formation. According to the structure of a National VI diesel engine exhaust pipe and SCR system, the nozzle is optimized by computational fluid dynamics (CFD) method to avoid the collision between the urea droplets and the exhaust pipe wall, to ensure that the exhaust gas and the urea droplets are as much as possible in full contact to ensure a sufficient urea pyrolysis. With the optimized nozzle, the NH₃ distribution uniformity of the inlet face of the SCR catalyst can increase from 0.58 to 0.92. Additionally, test verifications are implemented based on the spray particle size test and the engine bench tests; the results show that the Sauter mean diameter of the optimized nozzle is more decreased than the initial nozzle and that the NO_x conversion efficiency of the World Harmonized Transient Cycle (WHTC) and World Harmonized Stationary Cycle (WHSC) cycle improves by nearly 3%; additionally, it can also avoid deposit formation.

In this paper, deposits in exhaust pipes for automotive diesel engines were studied by various chemical analysis methods and a kind of analysis process to determine the compositions of organic matter was proposed. Firstly, the elements of the deposits were determined through the element analysis method. Then using characteristic absorption properties of organic functional groups to the infrared spectrum, the functional groups in the deposits were determined. Finally, by GC-MS (gas chromatography-mass spectrometry) test, the content of each main component was determined quantitatively. Element analysis results indicated that the deposits adsorbed metal impurities from fuel oil, lubricating oil, mechanical wear and urea water solution. The result of GC-MS test showed that the area percentage of cyanuric acid was the biggest (about 85%), the second was urea (about 4%), and the content of biuret and biurea was scarce.