Polypropylene (PP) belongs to the group of polymers characterized by low susceptibility to absorption of electromagnetic radiation in the infrared range (λ = 1064 nm). This research consisted of assessing the possibility of using silica waste from the metallurgic industry as an additive for PP laser marking. The modifier was introduced into the polymer matrix in the range from 1 to 10 wt%. The effects of laser radiation were assessed based on colorimetric tests and microscopic surface analysis. The mechanical properties of the composites were determined during the static tensile tests. The thermal properties were investigated via differential scanning calorimetry. It was found that the introduction of silica waste into polypropylene allows for the effective marking of sample surfaces with the use of a laser beam. The greatest contrast between the graphic symbol and the background was obtained for silica contents of 3 and 5 wt%, with the use of a low-speed laser head and a strong concentration of the laser beam. The application of silica caused an increase in the modulus of elasticity and the tensile strength of the composite samples. Increases in the crystallization temperature and the degree of crystallinity of the polymer matrix were also observed. It was found that silica waste can act as multifunctional additive for polypropylene.
Laser marking of polymer materials is a technology that is increasingly used in industry. Polypropylene (PP) shows a low ability to absorb electromagnetic radiation in the near-infrared range (λ = 1064 nm). The paper presents the influence of the surface condition of white-colored polypropylene moldings on the efficiency of their marking with a laser beam. In addition, the operation of the commercial laser marking additive (LMA) Lifolas M 117009 UN, intended to support the process of laser marking of polyolefin surfaces, was verified. The study is an attempt to combine laser operating parameters, material, and geometric properties of PP moldings to obtain the expected quality of graphic symbols. The test samples were made by injection molding method with the use of a specially designed modular injection mold. The molding cavities were prepared with various methods of metal processing, thanks to which obtained moldings differed in surface condition. The marking effects were assessed based on colorimetric tests and digital image analysis. The 0.5 wt% LMA content resulted in obtaining a graphic sign with high contrast in comparison to the background. The gradual increase in the modifier content resulted in a further increase in contrast. These values depended on the degree of surface finish of the samples, and therefore on the roughness parameters. Samples with a rough surface finish showed higher contrast compared to surfaces with a high surface finish. It was also found that for the analyzed moldings, the laser-marking process should be performed with the use of a low head velocity (450–750 mm/s) and a high concentration of the laser beam (0.03–0.05 mm).
1 May 2025 in Advances in Science and Technology Research Journal
The study investigated the influence of the structural steel grade and the hot-dip galvanizing process time on the thickness and surface condition of the zinc coating. The S235, S355 and S460 steels were used for the study. The prepared square-shaped test samples with a thickness of 12 mm were...
1 November 2024 in Advances in Science and Technology Research Journal
The dimensional accuracy of injection molded parts plays an increasingly significant role in the plastics processing industry, as is the utilization of recycled raw materials. To obtain the desired dimensions and properties of injection moldings, various material modification methods are used...
1 January 2026 in Advances in Science and Technology Research Journal
Surface roughness is one of the key criteria for assessing surface condition across various industries. Even slight changes in topography can significantly affect the functional properties of components. Therefore, accurate roughness measurements require a comprehensive understanding of how...
1 September 2024 in Advances in Science and Technology Research Journal
The most frequently used method for measuring surface roughness is profilographometry. However, with complex and non-homogeneous surfaces, this method may be subject to large errors because of its contact nature and limitations related to the geometry of the measuring head. In this study, the...