The Arctic is very susceptible to climate change and thus is warming much faster than the rest of the world. Clouds influence terrestrial and solar radiative fluxes and thereby impact the amplified Arctic warming. The partitioning of thermodynamic phases (i.e., ice crystals and water droplets) within mixed-phase clouds (MPCs) especially influences their radiative properties. However, the processes responsible for ice crystal formation remain only partially characterized. In particular, so-called secondary ice production (SIP) processes, which create supplementary ice crystals from primary ice crystals and the environmental conditions that they occur in, are poorly understood. The microphysical properties of Arctic MPCs were measured during the Ny-Ålesund AeroSol Cloud ExperimENT (NASCENT) campaign to obtain a better understanding of the atmospheric conditions favorable for the occurrence of SIP processes. To this aim, the in situ cloud microphysical properties retrieved by a holographic cloud imager mounted on a tethered balloon system were complemented by ground-based remote sensing and ice-nucleating particle measurements. During the 6 d investigated in this study, SIP occurred during about 40 % of the in-cloud measurements, and high SIP events with number concentrations larger than 10 L⁻¹ of small pristine ice crystals occurred in 4 % of the in-cloud measurements. This demonstrates the role of SIP for Arctic MPCs. The highest concentrations of small pristine ice crystals were produced at temperatures between −5 and −3 ^∘C and were related to the occurrence of supercooled large droplets freezing upon collision with ice crystals. This suggests that a large fraction of ice crystals in Arctic MPCs are produced via the droplet-shattering mechanism. From evaluating the ice crystal images, we could identify ice–ice collision as a second SIP mechanism that dominated when fragile ice crystals were observed. Moreover, SIP occurred over a large temperature range and was observed in up to 80 % of the measurements down to −24 ^∘C due to the occurrence of ice–ice collisions. This emphasizes the importance of SIP at temperatures below −8 ^∘C, which are currently not accounted for in most numerical weather models. Although ice-nucleating particles may be necessary for the initial freezing of water droplets, the ice crystal number concentration is frequently determined by secondary production mechanisms.

Mixed‐phase clouds (MPCs), which consist of both supercooled cloud droplets and ice crystals, play an important role in the Earth's radiative energy budget and hydrological cycle. In particular, the fraction of ice crystals in MPCs determines their radiative effects, precipitation formation and lifetime. In order for ice crystals to form in MPCs, ice‐nucleating particles (INPs) are required. However, a large‐scale relationship between INPs and ice initiation in clouds has yet to be observed. By analyzing satellite observations of the typical transition temperature (T*) where MPCs become more frequent than liquid clouds, we constrain the importance of INPs in MPC formation. We find that over the Arctic and Southern Ocean, snow and sea ice cover significantly reduces T*. This indicates that the availability of INPs is essential in controlling cloud phase evolution and that local sources of INPs in the high‐latitudes play a key role in the formation of MPCs.

Clouds are the main source of uncertainties when projecting climate change. Mixed-phase clouds that contain ice and supercooled-liquid particles are especially hard to constrain, and climate models neither agree on their phase nor their spatial extent. This is problematic, as models that underestimate contemporary supercooled-liquid in mixed-phase clouds will underestimate future warming. Furthermore, it has recently been shown that supercooled-liquid water in mixed-phase clouds is not homogeneously-mixed, neither vertically nor horizontally. However, while there have been attempts at observationally constraining mixed-phase clouds to constrain uncertainties in future warming, all studies only use the phase of the interior of mixed-phase clouds. Here we show, using novel satellite observations that distinguish between cloud-top and interior phase in mixed-phase clouds, that mixed-phase clouds are more liquid at the cloud top globally. We use these observations to constrain the cloud top phase in addition to the interior in a global climate model, leading to +1 °C more 21^st century warming in NorESM2 SSP5-8.5 climate projections. We anticipate that the difference between cloud top and interior phase in mixed-phase clouds is an important new target metric for future climate model development, because similar mixed-phase clouds related biases in future warming are likely present in many climate models.

The optical-equivalent snow grain size affects the reflectivity of snow surfaces and, thus, the local surface energy budget in particular in polar regions. Therefore, the specific surface area (SSA), from which the optical snow grain size is derived, was observed for a 2-month period in central Antarctica (Kohnen research station) during austral summer 2013/14. The data were retrieved on the basis of ground-based spectral surface albedo measurements collected by the COmpact RAdiation measurement System (CORAS) and airborne observations with the Spectral Modular Airborne Radiation measurement sysTem (SMART). The snow grain size and pollution amount (SGSP) algorithm, originally developed to analyze spaceborne reflectance measurements by the MODerate Resolution Imaging Spectroradiometer (MODIS), was modified in order to reduce the impact of the solar zenith angle on the retrieval results and to cover measurements in overcast conditions. Spectral ratios of surface albedo at 1280 and 1100 nm wavelength were used to reduce the retrieval uncertainty. The retrieval was applied to the ground-based and airborne observations and validated against optical in situ observations of SSA utilizing an IceCube device. The SSA retrieved from CORAS observations varied between 27 and 89 m² kg⁻¹. Snowfall events caused distinct relative maxima of the SSA which were followed by a gradual decrease in SSA due to snow metamorphism and wind-induced transport of freshly fallen ice crystals. The ability of the modified algorithm to include measurements in overcast conditions improved the data coverage, in particular at times when precipitation events occurred and the SSA changed quickly. SSA retrieved from measurements with CORAS and MODIS agree with the in situ observations within the ranges given by the measurement uncertainties. However, SSA retrieved from the airborne SMART data slightly underestimated the ground-based results.