Research on carbon dioxide (CO₂) geological and biogeochemical cycles in the ocean is important to support the geoscience study. Continuous in-situ measurement of dissolved CO₂ is critically needed. However, the time and spatial resolution are being restricted due to the challenges of very high submarine pressure and quite low efficiency in water-gas separation, which, therefore, are emerging the main barriers to deep sea investigation. We develop a fiber-integrated sensor based on cavity ring-down spectroscopy for in-situ CO₂ measurement. Furthermore, a fast concentration retrieval model using exponential fit is proposed at non-equilibrium condition. The in-situ dissolved CO₂ measurement achieves 10 times faster than conventional methods, where an equilibrium condition is needed. As a proof of principle, near-coast in-situ CO₂ measurement was implemented in Sanya City, Haina, China, obtaining an effective dissolved CO₂ concentration of ~950 ppm. The experimental results prove the feasibly for fast dissolved gas measurement, which would benefit the ocean investigation with more detailed scientific data.

To achieve multi-gas measurements of quartz-enhanced photoacoustic spectroscopy (QEPAS) sensors under a frequency-division multiplexing mode with a narrow modulation frequency interval, we report a frequency-domain detection method. A CH₄ absorption line at 1653.72 nm and a CO₂ absorption line at 2004.02 nm were investigated in this experiment. A modulation frequency interval of as narrow as 0.6 Hz for CH₄ and CO₂ detection was achieved. Frequency-domain 2f signals were obtained with a resolution of 0.125 Hz using a real-time frequency analyzer. With the multiple linear regressions of the frequency-domain 2f signals of various gas mixtures, small deviations within 2.5% and good linear relationships for gas detection were observed under the frequency-division multiplexing mode. Detection limits of 0.6 ppm for CH₄ and 2.9 ppm for CO₂ were simultaneously obtained. With the 0.6-Hz interval, the amplitudes of QEPAS signals will increase substantially since the modulation frequencies are closer to the resonant frequency of a QTF. Furthermore, the frequency-domain detection method with a narrow interval can realize precise gas measurements of more species with more lasers operating under the frequency-division multiplexing mode. Additionally, this method, with a narrow interval of modulation frequencies, can also realize frequency-division multiplexing detection for QEPAS sensors under low pressure despite the ultra-narrow bandwidth of the QTF.