A series of new films with antibacterial properties has been obtained by means of solvent casting method. Biodegradable materials including polylactide (PLA), quercetin (Q) acting as an antibacterial compound and polyethylene glycol (PEG) acting as a plasticizer have been used in the process. The effect of quercetin as well as the amount of PEG on the structural, thermal, mechanical and antibacterial properties of the obtained materials has been determined. It was found that an addition of quercetin significantly influences thermal stability. It should be stressed that samples containing the studied flavonoid are characterized by a higher Young modulus and elongation at break than materials consisting only of PLA and PEG. Moreover, the introduction of 1% of quercetin grants antibacterial properties to the new materials. Recorded results showed that the amount of plasticizer did not influence the antibacterial properties; it does, however, cause changes in physicochemical properties of the obtained materials. These results prove that quercetin could be used as an antibacterial compound and simultaneously improve mechanical and thermal properties of polylactide-based films.
This article presents the initial test results examining basic technological factors, such as type of modifying agent and seasoning time, which influence properties of adhesive epoxide compositions. The aim of the study was to prepare adhesive compositions with 2% content of the selected natural fillers (montmorillonite NanoBent ZR-2, ground chalk (powder)—CaCO3, and activated carbon powder C) and to examine their strength properties. A polymeric matrix used to prepare an adhesive composition consisted of the epoxide resins used in industry: Epidian 5 and Epidian 53 cured by addition of an aminomethyl group, where curing occurred through the Mannich reaction. A composition of epoxide resins with a curing agent and without any modifying agents was used as reference. The examinations described in the present article aimed to show the significance of the impact of the fillers used on the strength properties of the examined compositions. A fracture surface of epoxide adhesive compositions modified with the selected fillers was tested by means of a scanning electron microscope.
The aim of the study was to establish the influence of poly(ethylene glycol) (PEG) on the properties of potential biodegradable packaging materials with antibacterial properties, based on polylactide (PLA) and tea tree essential oil (TTO). The obtained polymeric films consisted of PLA, a natural biocide, and tea tree essential oil (5–20 wt. %) was prepared with or without an addition of 5 wt. % PEG. The PLA-based materials have been tested, taking into account their morphology, and their thermal, mechanical and antibacterial properties against Staphylococcus aureus and Escherichia coli. It was established that the introduction of a plasticizer into the PLA–TTO systems leads to an increase in tensile strength, resistance to deformation, as well an increased thermal stability, in comparison to films modified using only TTO. The incorporation of 5 wt. % PEG in the PLA solution containing 5 wt. % TTO allowed us to obtain a material exhibiting a satisfactory antibacterial effect on both groups of representative bacteria. The presented results indicated a beneficial effect of PEG on the antibacterial and functional properties of materials with the addition of TTO.