A mixed culture of A. ferrooxidans and A. thiooxidans isolated from a coal gangue dump was used to bioleach coal gangue in a column reactor to investigate the leaching of elements. The changes of metal ions (Fe, Mn and Cr) and sulfate in the leaching solution, elemental composition, mineral components and sulfur speciation of the coal gangue before and after bioleaching were analyzed by atomic absorption, anion chromatography, XRF, XRD and XPS. The results show that the mixed culture could promote the release of metal ions in coal gangue, with a leaching concentration of Fe > Mn > Cr. EC and Eh have significantly increased with the increase of metal ion concentrations in the leaching solution. XRF analyses show that the contents of Fe, Mn and S decreased in coal gangue after bioleaching. XRD results suggest that the bioleaching has impacts on minerals in coal gangue, particularly the Fe-containing components. XPS analyses show that sulfur speciation in the raw gangue samples was associated with sulfate, dibenzothiophene and pyrite sulfur. After continuous leaching by the mixed culture, the total sulfur, pyrite sulfur and sulfate sulfur in coal gangue decreased from 2.06% to 1.18%, 0.66% to 0.14% and 1.02% to 0.52%. The desulfurization rates of the pyrite and sulfate were 78.79% and 49.02 %. It is concluded that the mixed culture of these two microorganisms could effectively leach metals from coal gangue coupling with the oxidation of sulfide to sulfate. This study has provided fundamental information as a potential application in the recovery of valuable metals from coal gangue or environmental remediation related to gangue in the future.

Coalbed methane (CBM) is an unconventional natural gas resource. CBM mining releases a large amount of coproduced water, and the trace elements of CBM coproduced water can provide a basis for the exploration and development of CBM. The contents of eight major trace elements in the produced water from wellhead were tested and analyzed based on seven CBM wells in Tiefa Basin. The research indicates that Sr and Ba are the dominant trace elements with the highest concentrations in produced water. There is a positive correlation among Li, Sr, and Rb by cluster analysis and correlation analysis, which may be affected by the total dissolved solids and pH in the groundwater. The contents of Li, Sr, and Ba increase with the burial depth of coal seam and could be influenced by the fault. The gas production of CBM wells is affected by the depth of the coal seams, and there is no significant correlation between water production and the coal seam depth. However, faults have an important impact on gas and water production. The productivity of coalbed methane is affected by hydrogeological conditions and structure because the productivity of CBM wells located in different tectonic locations varies with the change of Li, Sr, and Ba contents.

The study of pore characteristics in tectonic coal is essential for a deeper understanding of gas diffusion, seepage, and other transport processes within coal seams, and plays a crucial role in the development of coalbed methane resources. Based on low-temperature N₂ and CO₂ adsorption experiments, this study investigated the pore structure characteristics of four tectonic coal samples collected from the Hegang and Jixi basins in China. The results show that the mylonitic coal sample exhibits a clear capillary condensation and evaporation phenomenon around a relative pressure (P/P₀) of 0.5. The degree of tectonic deformation in coal has a significant impact on its pore characteristics. As the degree of deformation increases, both the pore volume and specific surface area of the coal gradually increase. The pore volume and specific surface area of micropores are primarily concentrated in pores with diameters of 0.5–0.7 nm and 0.8–0.9 nm, while those of mesopores are mainly distributed in pores with diameters of 2.3–6.2 nm. The proportion of pore volume and specific surface area contributed by micropores is much greater than that of mesopores. The fractal dimension is positively correlated with the degree of tectonic deformation in coal. As the fractal dimension increases, the average pore diameter decreases, closely tied to the destruction and reconstruction of the coal’s pore structure under tectonic stress. These findings will contribute to a deeper understanding of the pore structure characteristics of tectonic coal and effectively advance coalbed methane development.

The research of pore and permeability characteristics of tight sandstone reservoirs in coal-measure is critical for coal-measure gas development. In this study, the pore systems of tight sandstones were studied based on low-field nuclear magnetic resonance (LF-NMR) data. The permeability of tight sandstones was obtained by the tester based on the pulse transient method. The permeability variation with the effective stress, grains, and pore characteristics was analyzed. The results show that the tight sandstone reservoirs in the coal-measure have low total porosity (2.80–4.14%), low effective porosity (0.51–1.56%), and low permeability (0.351 × 10⁻⁶–13.910 × 10⁻⁶ um²). LF-NMR T₂ spectra of the testing sandstones show that the micropores are the most developed, but most of the micropores are immovable pores. The pore characteristics are significantly affected by the grain size of sandstones. The pore connectivity ranks from good to poor with decreasing sandstone particle size. The total porosity and effective porosity increase with the grain size. There is a near-linear negative relationship between permeability and effective stress when the effective stress is between 405 psi and 808 psi. The greater the number of movable pores and the larger the effective porosity, the bigger the permeability of the sandstone. The effective porosity of sandstones is a sensitive indicator for evaluating the permeability of tight sandstone reservoirs. The stress sensitivity coefficient of permeability (S_s) increases with the increase of the effective stress. The sandstone with lower permeability, smaller effective porosity, and finer grains has a higher S_s. The particle size of sandstone from coal-measure has a great influence on both permeability and S_s. The findings will provide a better understanding of the characterization of pore structure and permeability in the process the coal-measure gas extraction, which is useful for the efficient development of coal-measure gas.