Bulk chemicals such as ethylene glycol (EG) can be industrially synthesized from either ethylene or syngas, but the latter undergoes a bottleneck reaction and requires high hydrogen pressures. We show that fullerene (exemplified by C 60 ) can act as an electron buffer for a copper-silica catalyst (Cu/SiO 2 ). Hydrogenation of dimethyl oxalate over a C 60 -Cu/SiO 2 catalyst at ambient pressure and temperatures of 180° to 190°C had an EG yield of up to 98 ± 1%. In a kilogram-scale reaction, no deactivation of the catalyst was seen after 1000 hours. This mild route for the final step toward EG can be combined with the already-industrialized ambient reaction from syngas to the intermediate of dimethyl oxalate.
18 August 2015 in Journal of Materials Chemistry A
Low-cost solution-processed copper iodide replaces PEDOT:PSS in inverted planar heterojunction perovskite solar cells with high efficiency and enhanced stability.
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