Urban mineral resources, with their significant recycling potential, have increasingly accumulated worldwide and become an important source for extracting valuable metals, particularly critical rare dispersed metals (CRDMs) such as gallium, germanium, and indium. As the electronics industry continues to grow rapidly, the demand for CRDMs is rising. However, CRDMs in primary mineral resources are often found in small, dispersed concentrations, making extraction challenging. In contrast, urban mineral resources contain relatively higher concentrations of CRDMs, making their comprehensive exploitation more advantageous than that of primary minerals. This paper underscores the importance of metal recycling by examining the current state of e-waste recycling from urban mineral resources in China. It outlines the general process of e-waste recycling, briefly compares the advantages and disadvantages of common metal recycling methods, and summarizes the current status of CRDMs recycling from various electronic wastes. Finally, this paper discusses the development trends and future prospects of metal recycling technology in urban minerals.

Photocatalytic degradation of organic pollutants in wastewater is recognized as a promising technology. However, photocatalyst Bi₂O₃ responds to visible light and suffers from low quantum yield. In this study, the α-Bi₂O₃ was synthetized and used for removing Cl⁻ in acidic solutions to transform BiOCl. A heterostructured α-Bi₂O₃/BiOCl nanosheet can be fabricated by coupling Bi₂O₃ (narrow band gap) with layered BiOCl (rapid photoelectron transmission). During the degradation of Rhodamine B (RhB), the Bi₂O₃/BiOCl composite material presented excellent photocatalytic activity. Under visible light irradiation for 60 min, the Bi₂O₃/BiOCl photocatalyst delivered a superior removal rate of 99.9%, which was much higher than pristine Bi₂O₃ (36.0%) and BiOCl (74.4%). Radical quenching experiments and electron spin resonance spectra further confirmed the dominant effect of electron holes h⁺ and superoxide radical anions ·O₂⁻ for the photodegradation process. This work develops a green strategy to synthesize a high-performance photocatalyst for organic dye degradation.

The increasing threat of chloride ions (Cl⁻) has led researchers to explore efficient removal technologies. Sewage treatment with a double-layer hydroxide/oxide (LDH/LDO) is receiving increasing attention. In this work, Mg-Al LDO adsorbents were produced by the calcination of the Mg-Al LDH precursor, which was constituted by improved coprecipitation. The influence of calcination temperature, calcination time, adsorbent dosage, Cl⁻ initial concentration, contact time, and adsorption temperature on Cl⁻ elimination was investigated systematically. The experimental results showed that a better porous structure endowed the Mg-Al LDO with outstanding adsorption properties for Cl⁻. The adsorption process was well matched to the pseudo-second-order kinetics model and the Freundlich model. Under optimal conditions, more than 97% of the Cl⁻ could be eliminated. Moreover, the removal efficiency was greater than 90% even after 11 adsorption–desorption cycles. It was found that the electrostatic interaction between Cl⁻ and the positively charged Mg-Al LDO laminate, coupled with the reconstruction of the layer structure, was what dominated the Cl⁻ removal process.

Chitosan (CS) is a natural and low-cost adsorbent for capturing metal ions and organic compounds. However, the high solubility of CS in acidic solution would make it difficult to recycle the adsorbent from the liquid phase. In this study, the CS/Fe₃O₄ was prepared via Fe₃O₄ nanoparticles immobilized onto a CS surface, and the DCS/Fe₃O₄-Cu was further fabricated after surface modification and the adsorption of Cu ions. The meticulously tailored material displayed the sub-micron size of an agglomerated structure with numerous magnetic Fe₃O₄ nanoparticles. During the adsorption of methyl orange (MO), the DCS/Fe₃O₄-Cu delivered a superior removal efficiency of 96.4% at 40 min, which is more than twice the removal efficiency of 38.7% for pristine CS/Fe₃O₄. At an initial MO concentration of 100 mg L⁻¹, the DCS/Fe₃O₄-Cu exhibited the maximum adsorption capacity of 144.60 mg g⁻¹. The experimental data were well explained by the pseudo-second-order model and Langmuir isotherm, suggesting the dominant monolayer adsorption. The composite adsorbent still maintained a large removal rate of 93.5% after five regeneration cycles. This work develops an effective strategy to simultaneously achieve high adsorption performance and convenient recyclability for wastewater treatment.

This paper presents the development of an environmentally friendly, small molecular depressant citrus pectin for improving the recovery of cassiterite resources. Citrus pectin extracted from citrus peel was utilized as the depressant, and it demonstrated significant potential in separating calcite from cassiterite in micro-flotation tests. The molecular weight of the citrus pectin extracted in this paper decreased from 11,485,412 Da to 32,959 Da compared to commercial pectin, resulting in the depressant efficiency of the reagent. The results of a zeta potential and adsorption test indicated that citrus pectin had less and weaker adsorption on the cassiterite surface and could be replaced with NaOL. The chemical adsorption process of citrus pectin on the surface of calcite was determined through FTIR spectroscopy analysis. XPS analysis results indicated that the interaction between the carboxyl groups of citrus pectin and calcium atoms enables adsorption to occur. The AFM revealed that citrus pectin displayed a uniform and dense pattern of point-like adsorption on the surface of calcite. Micro-flotation experiments showed that cassiterite recovery of 80% can be obtained at a citrus pectin dosage of 10 mg/L. Citrus pectin has the advantages of being low-cost, highly selective, and environmentally suitable, making it a promising alternative to conventional reagents.

Collectors commonly have synergetic effects in ores flotation. In this work, a waste engine oil (WEO) was introduced as a collector to an ilmenite flotation system with sodium oleate (NaOL). The results show that the floatability of ilmenite was significantly improved by using WEO and NaOL as a combined collector. The recovery of ilmenite was enhanced from 71.26% (only NaOL) to 93.89% (WEO/NaOL combined collector) at the pH of 6.72. The optimum molar ratio of NaOL to WEO was about 2.08 to 1. The WEO and NaOL also have synergetic effects for the collection of ilmenite, because to obtain the ilmenite recovery of 53.96%, the dosage of 45 mg/L NaOL is equal to 38.56 mg/L WEO/NaOL combined collector (30 mg/L NaOL + 8.56 mg/L WEO). In other words, 15 mg/L of NaOL can be replaced by 8.56 mg/L of WEO. It is an effective way to reduce the dosage of the collector and reuse WEO. Therefore, it is a highly valuable and environmentally friendly approach for WEO reuse. WEO mainly consists of oxygen functional groups, aromatics, and long-chain hydrocarbons, especially for the RCONH₂ and RCOOH, thereby forming a strong interaction on the ilmenite surface. The adsorption mechanism of waste engine oil and sodium oleate on the ilmenite surface is mainly contributed by chemical adsorption. Therefore, WEO exhibits superior synergistic power with NaOL as a combined collector. Herein, this work provided an effective collector for ilmenite flotation and a feasible approach for reducing NaOL dosage and recycling WEO.