In order to improve the wear and corrosion resistance of micro-arc oxidation (MAO) coating on a Ti-5Al-1V-1Sn-1Zr-0.8Mo alloy, 0–0.20 g/L graphene was added to the electrolyte to prepare micro-arc oxidation coating. The thickness, roughness, micro-morphology, and composition of the MAO coating were characterized, and the wear and corrosion resistance of the coating was tested and analyzed. The results show that with 0.05 g/L of graphene in the electrolyte, the roughness of the coating decreased from 56.76 μm to 31.81 μm. With the increase in the addition of graphene, the microstructure of the coating became more compact, the diameter of micro-holes and micro-cracks decreased, and the corrosion resistance of the coating improved. The wear tests showed that the mass loss of the coating at the early wear stage (0~100 revolutions) was greater than that at the later stage (100~250 revolutions), and the wear resistance of the coating obtained by the addition of 0.10 g/L of graphene was the highest. With 0.10 g/L of graphene, the adhesion force between the coating and the substrate alloy is the largest, reaching 57.1 N, which is 9.98 N higher than that without graphene. After salt spray corrosion for 480 h, the coating with graphene has better corrosion resistance than that of a graphene-free coating.

Ceramic coatings on R60705 zirconium alloy were prepared on the surface by the micro-arc oxidation (MAO) technique in electrolytes containing Na₂SiO₃, NaOH, and Na₂EDTA. The growth behavior of the MAO ceramic coatings at different stages, including growth rate, microstructure, and phase composition, was investigated using the method of direct observation of the boundary area. The results showed that the growth of the MAO coatings on R60705 zirconium alloy occurred in both inward and outward directions. At an oxidation time of 5 min, the thickness of the oxidation layer increased fastest, reaching 103.43 μm, with a growth rate of 0.345 μm/s. After 5 min, the growth rate decreased and tended to level off around 15 min, with a thickness and growth rate of 162.7 μm and 0.181 μm/s, respectively. The total thickness of the coatings continuously increased throughout the process, with the outward growth thickness always higher than the inward growth thickness. The composition of the zirconium alloy micro-arc oxidation coatings mainly consisted of monoclinic zirconia (m-ZrO₂), tetragonal zirconia (t-ZrO₂), and a small amount of SiO₂. The main elements in the coatings were Zr, O, and Si. The corrosion resistance of the zirconium alloy micro-arc oxidation coatings increased first and then decreased with increasing oxidation time, with a corrosion current density of 8.876 × 10⁻⁹ A·cm⁻² at 15 min, indicating the best corrosion resistance.

The micro-arc oxidation (MAO) technique was used to grow in situ oxidation coating on the surface of R60705 zirconium alloy in Na₂SiO₃, Na₂EDTA, and NaOH electrolytes. The thickness, surface morphology, cross-section morphology, wear resistance, composition, and structure of the micro-arc oxidation coating were analyzed by an eddy current thickness measuring instrument, XPS, XRD, scanning electron microscopy, energy spectrometer, and wear testing machine. The corrosion resistance of the coating was characterized by a polarization curve and electrochemical impedance spectroscopy (EIS). The results show that, with the increase in frequency, the single-pulse discharge energy decreases continuously, and the coating thickness shows a decreasing trend, from the highest value of 152 μm at 400 Hz to the lowest value of 87.5 μm at 1000 Hz. The discharge pore size on the surface of the coating gradually decreases, and the wear resistance and corrosion resistance of the coating first increase and then decrease. The corrosion resistance is the best when the frequency is 400 Hz. At this time, the corrosion potential is −0.215 V, and the corrosion current density is 2.546 × 10⁻⁸ A·cm⁻². The micro-arc oxidation coating of zirconium alloy is mainly composed of monoclinic zirconia (m-ZrO₂) and tetragonal zirconia (t-ZrO₂), in which the content of monoclinic zirconia is significantly more than that of tetragonal zirconia.

This study presents a strategy for the preparation of multiscale α phase by high/low-temperature two-step aging in metastable β titanium alloy, Ti-15Mo-3Al-2.7Nb-0.2Si. The purpose of high-temperature aging is to obtain a number of micro-scale secondary α phases (α_S), besides precipitation-free zones (PFZs). After that, in the second stage of low-temperature aging, the nano-scale tertiary α phase (α_T) precipitates in the PFZs. The second-step aging temperature and the time at low temperature will have an important effect on α_T. On the one hand, with the extension of aging time, the morphology of α_T changes from dot-like to needle-like. Secondly, the increase of the second-step aging temperature will promote precipitation of α_T in PFZs. The strength increases gradually with the accelerated precipitation of α_T, and good plasticity is still maintained. The effect of multiscale α on fracture behavior was investigated by in situ tensile testing. Results show that cracks form a transgranular fracture along the slip line after solution treatment. After first-step aging, the crack easily passes through α_S and forms an intergranular fracture. After second-step aging, the formation of multiscale α phase has a stronger effect in hindering the crack growth, which leads to crack propagation mainly by transgranular fracture. Overall, this study demonstrates that the alloy can be heat-treated to achieve an excellent match between strength and ductility, which is expected to meet the application requirements of structural materials of the new generation of aircraft.