The physical mechanisms responsible for the electrical orientation and electrical rotation of metal nanowires suspended in an electrolyte as a function of frequency of the applied ac electric field are examined theoretically and experimentally. The alignment of a nanowire in an ac field with a fixed direction is called electro-orientation. The induced constant rotation of a nanowire in a rotating electric field is called electrorotation. In both situations, the applied electric field interacts with the induced charge in the electrical double layer at the metal-electrolyte interface, causing rotation due to the torque on the induced dipole, and also from induced-charge electro-osmotic flow around the particle. First, we describe the dipole theory that describes electro-orientation and electrorotation of perfectly polarizable metal rods. Second, based on a slender approximation, an analytical theory that describes induced-charge electro-orientation and electrorotation of metal nanowires is provided. Finally, experimental measurements of the electro-orientation and electrorotation of metal nanowires are presented and compared with theory, providing a comprehensive study of the relative importance between induced-dipole rotation and induced-charge electro-osmotic rotation.

This study explores the effect of steam addition during carbonation on the multicyclic performance of limestone under calcium looping conditions compatible with (i) CO₂ capture from postcombustion gases (CCS) and with (ii) thermochemical energy storage (TCES). Steam injection has been proposed to improve the CO₂ uptake capacity of CaO-based sorbents when the calcination and carbonation loops are carried out in CCS conditions: at moderate carbonation temperatures (∼650 °C) under low CO₂ concentration (typically ∼15% at atmospheric pressure). However, the recent proposal of calcium-looping as a TCES system for integration into concentrated solar power (CSP) plants has aroused interest in higher carbonation temperatures (∼800–850 °C) in pure CO₂. Here, we show that steam benefits the multicyclic behavior in the milder conditions required for CCS. However, at the more aggressive conditions required in TCES, steam essentially has a neutral net effect as the CO₂ uptake promoted by the reduced CO₂ partial pressure but also is offset by the substantial steam-promoted mineralization in the high temperature range. Finally, we also demonstrate that the carbonation rate depends exclusively on the partial pressure of CO₂, regardless of the diluting gas employed.