H 2 TiO 3 (HTO) is considered to be one of the most promising adsorbents for lithium recovery from aqueous lithium resources duo to its highest theoretical adsorption capacity.
1 February 2022 in Journal of Colloid and Interface Science
A simple and practical spray method is employed to prepare a PVDF/PFOTES-SiO2 superhydrophobic composite coating on the AZ31B Mg alloy substrate. The morphology, composition, and water contact angle (CA) were measured by Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscope (FESEM) and contact angle measuring instrument. Hydrophilic nano-SiO2 is modified by PFOTES to obtain hydrophobicity. The influence of the mass of PFOTES-SiO2 to PVDF on the hydrophobic properties was studied. The wear resistance and stability of the composite coating have been investigated by immersion test, cross-cut adhesion test and friction test. Additionally, the corrosion resistance was measured by electrochemical workstation and salt spray corrosion test. The CA of PVDF/PFOTES-SiO2 coating is 161.3° and the sliding angle (SAs) is less than 2°. After 10× the sandpaper friction test, the superhydrophobic contact angle of the coating remained above 155°, and the sliding angle was less than 5°, which indicated that the prepared coating is a strong superhydrophobic coating with good wear resistance. The results of the electrochemical tests show that the superhydrophobic coating improved the anti-corrosion performance of Mg alloy, and the water contact angle is greater than 150° after 168 h salt spray corrosion test. Due to its excellent superhydrophobicity, wear resistance and anti-corrosion properties, the robust PVDF/PFOTES-SiO2 coating is considered to have great potential for future applications in the automotive and marine industries.
Solid–liquid phase change materials (PCMs), when used as solvents in organic thermochromic composite systems, often suffer from leakage issues, which degrade their reversible color‐changing capability. Although encapsulation and porous composite shape‐stabilization techniques can enhance the structural integrity of PCMs, these methods are often complex, limited to lab‐scale production, and costly. Hereby, a facile eutectic strategy is presented to develop leakage‐free PCMs for stabilizing organic thermochromic composites by integrating organic lauric acid (LA) and inorganic sodium acetate trihydrate (SAT). Molecular dynamics simulations reveal significantly enhanced intermolecular interactions between SAT and LA compared to those between LA molecules. These strengthened intermolecular interactions endow the SAT/LA eutectic with excellent shape stability, preventing leakage and phase separation. Benefiting from the superior properties of the SAT/LA eutectic, the resulting thermochromic composites exhibit outstanding shape stability, cyclically reversible thermochromic performance, and considerable latent heat capacity. Leveraging these advantages, applications in temperature indicators, thermally regulated quick response codes, information encryption, and data storage/disguise are successfully demonstrated. This work, guided by molecular dynamics simulations, offers a promising approach to designing industrial‐scale, cost‐effective, shape‐stabilized thermochromic materials for temperature indication and information encryption.