This study explores the mechanical properties, as well as the water-reducing and setting delay mechanism, of a novel xylonic acid-based water reducer applied to cementitious materials. Four xylonic acid water reducers were synthesized in this study: XACa (PX) from pure xylose, XACa (HS) from hemicellulose hydrolysate, XANa (PX) from pure xylose, and XANa (HS) from hemicellulose hydrolysate. These were generated through the whole-cell catalysis of Gluconobacter oxydans bacteria, using pure xylose and hemicellulose hydrolysate as substrates. The findings indicate that the xylonic acid-based water reducer can attain a water-reducing capability between 14% and 16% when the dosage (expressed as a mass fraction of cement) is roughly 0.2%. In initial and final setting tests, XACa (PX) demonstrated a pronounced retarding influence at admixture levels below 0.15%, reaching its apex at 0.10%. This delayed the initial setting time by 76% and the final setting time by 136% relative to the control group. However, a slight pro-setting effect was noted beyond a 0.2% dosage. In the compressive and flexural tests of concrete, under the same slump, the XA group improved its mechanical properties by 5% to 10% compared to the SodiuM lignosulfonate (SL) group. In the air content and chloride ion migration resistance tests, the XA group reduced the air content by 38% compared to the SL group, but also increased the data of rapid chloride migration (DRCM) by 16%. Characterization studies revealed that the carboxyl and hydroxyl groups in xylonic acid undergo chemisorption with the Si-O bonds on the surface of cement particles. These groups interact with the Si-O bonds on cement particles, contributing to water-reducing effects and delaying the setting process by impeding Ca2+ ion aggregation in the calcium-silicate-hydrate gel. Its significant water-reducing effect, adjustable setting time, and excellent mechanical and durability properties suggest its viability as an alternative to lignosulfonate series water-reducing agents.
Owing to its high efficiency and low environmental impact, superhydrophobic deicing coating material has a bright future for application on road pavements. In this paper, a heterogeneous nucleation ice crystal growth model is proposed, with particular focus on the effect of surface roughness and the contact angle. The ice suppression mechanism of superhydrophobic materials is determined by this model and experimentally verified. The experimental results of the water contact angle and anti-skid tests illustrated that the prepared TiO2–octadecanoic acid coating material has a contact angle greater than 150° and good skid resistance. The freezing test confirms that the applied coating on the surface can effectively delay the crystallization of water droplets and maintain the waterdrop’s semi-spherical shape after freezing. The microstructure observation demonstrates the TiO2–octadecanoic acid material has a good micro-nano mastoid structure. Consequently, the proposed coating materials could possibly be utilized for effectively enhancing the deicing performance of pavements.
According to the vehicle dynamics model and the requirements of reliable safety and minimal time, the path planning problem of parking in different types of parking spaces is solved by obstacle avoidance analysis and motion analysis in the case of the optimal solution, and the parking trajectory from the initial position to the designated parking space is obtained. In the static situation, different parking spaces in the parking space are occupied; analyze the parking space type, parking space left and right occupancy situation, and the distance between the vacant parking space and the starting point location of unoccupied cars; and establish the attribute information matrix R0 of the vacant parking space and calculate the KMO value of the matrix R0. This is completed to determine the weak correlation between the attributes of the vacant parking space and use the matrix R0 as the original evaluation matrix of the entropy weight method, using the entropy weight method to calculate the three attributes of parking space type, parking space left and right occupancy situation, and distance between starting point and parking space. These results are weighted in the optimal parking space selection process, the difficulty score of the vacant parking space is determined, and the optimal parking space is determined through the ranking of the scores. In the dynamic case, the number of parking spaces and parking space usage will change over time, with the help of the Bayesian network, the existing parking spaces and number of spaces in the parking lot at the previous moment are learned according to the computer clock, which can be used to reason about the number of parking spaces and parking space availability in the parking lot at the next moment. The weights of the three attributes of parking space type, parking space left and right situation, and distance between the starting point and parking space are updated in the case of a dynamic change of parking space, and then the parking difficulty score of a new vacant parking space using the entropy weight method is used to select the optimal parking space in the dynamic situation. The optimized parking path planning and parking space selection method could contribute to enhancing parking efficiency for the sustainable management of indoor parking lots.
Superhydrophobic coating ice suppression is an advanced and durable technology that shows great potential for application on pavements. Although many researchers have conducted experimental and theoretical validations to confirm the effectiveness of superhydrophobic surfaces in actively suppressing ice formation, there are still some who remain skeptical. They argue that the roughness of the surface may increase ice adhesion due to the mechanical interlocking effect of condensation droplets in low-temperature and high-humidity environments. In this study, we present a comprehensive investigation of a novel superhydrophobic coating specifically designed for pavement surfaces, aiming to address the question of its active anti-icing/ice-sparing capabilities in a condensing environment. The changes in contact angle before and after condensation for four material surfaces with varying wettability were investigated, as well as the morphology and ice adhesion of liquid water after it freezes on the material surface. The findings reveal that the proposed superhydrophobic coating for pavements effectively prevents condensate droplets from infiltrating the surface structure, resulting in delaying the surface icing time and reducing the attachment strength of the ice.
As a new type of backfill material, Self-compacting solidified soil (SCSS) takes the abandoned slurry of cast-in-place piles after dewatering and reduction as the main raw material, which brings a problem of coordinating the working performance with the mechanical property under the condition of high mobility. In this paper, hydroxypropyl methyl cellulose (HPMC) and metakaolin were introduced as additives to solve this problem. First, the workability and mechanical properties of SCSS were regulated and optimized by means of the water seepage rate test, the flowability test, and the unconfined compressive strength test. Second, this study also used X-ray diffraction (XRD) and scanning electron microscopy (SEM) to investigate the effects of HPMC and metakaolin on the physical phase and microstructure of SCSS. In this way, the results showed that there was a significant impact on the flowability of SCSS, that is, when the dosage reached 0.3%, the water seepage rate of SCSS was reduced to less than 1%, and the compressive strength at 7 days reached its peak. At the same time, HPMC weakened the strength growth of SCSS in the age period of 7 days to 14 days. However, the addition of metakaolin promoted its compressive strength. XRD analysis showed that the additives had no significant effects on the physical phases. And, from the SEM results, it can be seen that although the water-retaining effect of HPMC makes hydration of cement more exhaustive, more ettringite (AFt) can be observed in the microstructure. In addition, it can be observed that the addition of metakaolin can generate more hydrated calcium silicate (C-S-H) due to the strong surface energy possessed by metakaolin. As a result of the above factors, SCSS filled the voids between particles and improved the interface structure between particles, thus enhanced the compressive strength.