As evidence for the devastating impacts of air pollution on human health continues to increase, improving urban air quality has become one of the most pressing tasks facing policy makers world-wide. Increasingly, and very often on the basis of conflicting and/or weak evidence, the introduction of green infrastructure (GI) is seen as a win–win solution to urban air pollution, reducing ground-level concentrations without imposing restrictions on traffic and other polluting activities. The impact of GI on air quality is highly context dependent, with models suggesting that GI can improve urban air quality in some situations, but be ineffective or even detrimental in others. Here we set out a novel conceptual framework explaining how and where GI can improve air quality, and offer six specific policy interventions, underpinned by research, that will always allow GI to improve air quality. We call GI with unambiguous benefits for air quality GI4AQ. However, GI4AQ will always be a third-order option for mitigating air pollution, after reducing emissions and extending the distance between sources and receptors.

Biosphere–atmosphere interactions play a critical role in governing atmospheric composition, mediating the concentrations of key species such as ozone and aerosol, thereby influencing air quality and climate. The exchange of reactive trace gases and their oxidation products (both gas and particle phase) is of particular importance in this process. The FORCAsT (FORest Canopy Atmosphere Transfer) 1-D model is developed to study the emission, deposition, chemistry and transport of volatile organic compounds (VOCs) and their oxidation products in the atmosphere within and above the forest canopy. We include an equilibrium partitioning scheme, making FORCAsT one of the few canopy models currently capable of simulating the formation of secondary organic aerosols (SOAs) from VOC oxidation in a forest environment. We evaluate the capability of FORCAsT to reproduce observed concentrations of key gas-phase species and report modeled SOA concentrations within and above a mixed forest at the University of Michigan Biological Station (UMBS) during the Community Atmosphere-Biosphere Interactions Experiment (CABINEX) field campaign in the summer of 2009. We examine the impact of two different gas-phase chemical mechanisms on modelled concentrations of short-lived primary emissions, such as isoprene and monoterpenes, and their oxidation products. While the two chemistry schemes perform similarly under high-NO_x conditions, they diverge at the low levels of NO_x at UMBS. We identify peroxy radical and alkyl nitrate chemistry as the key causes of the differences, highlighting the importance of this chemistry in understanding the fate of biogenic VOCs (bVOCs) for both the modelling and measurement communities.

Militaries around the world are a major source of carbon emissions, yet very little is known about their carbon footprint. Reliable data around military resource use and environmental damage is highly variable. Researchers are dependent upon military transparency, the context of military operations, and broader emissions reporting. While studies are beginning to emerge on global militaries and their carbon footprints, less work has focused on wartime emissions. We examine one sliver of the hidden carbon emissions of late‐modern warfare by focusing on the use of concrete “blast walls” by US forces in Baghdad over a five‐year period (2003–2008). This study uses a Life Cycle Assessment (LCA) to study one of the world's largest military carbon footprints of concrete, an infrastructural weapon in late‐modern urban counterinsurgencies. Moving beyond dominant discourses on climate‐security and “greening”, we present one of the first studies to expose direct and indirect military emissions resulting from combat.

Rising ozone (O₃) concentrations, coupled with an increase in drought frequency due to climate change, pose a threat to plant growth and productivity which could negatively affect carbon sequestration capacity of Northern Hemisphere (NH) forests. Using long‐term observations of O₃ mixing ratios and soil water content (SWC), we implemented empirical drought and O₃ stress parameterizations in a coupled stomatal conductance–photosynthesis model to assess their impacts on plant gas exchange at three FLUXNET sites: Castelporziano, Blodgett and Hyytiälä. Model performance was evaluated by comparing model estimates of gross primary productivity (GPP) and latent heat fluxes (LE) against present‐day observations. CMIP5 GCM model output data were then used to investigate the potential impact of the two stressors on forests by the middle (2041–2050) and end (2091–2100) of the 21st century. We found drought stress was the more significant as it reduced model overestimation of GPP and LE by ~11%–25% compared to 1%–11% from O₃ stress. However, the best model fit to observations at all the study sites was obtained with O₃ and drought stress combined, such that the two stressors counteract the impact of each other. With the inclusion of drought and O₃ stress, GPP at CPZ, BLO and HYY is projected to increase by 7%, 5% and 8%, respectively, by mid‐century and by 14%, 11% and 14% by 2091–2100 as atmospheric CO₂ increases. Estimates were up to 21% and 4% higher when drought and O₃ stress were neglected respectively. Drought stress will have a substantial impact on plant gas exchange and productivity, off‐setting and possibly negating CO₂ fertilization gains in future, suggesting projected increases in the frequency and severity of droughts in the NH will play a significant role in forest productivity and carbon budgets in future.