In recent years, the use of magnetic biochar in wastewater treatment has shown significant effects and attracted scholars’ attention. However, due to the relatively short research time and the lack of systematic summaries, it is difficult to provide a more in-depth analysis. This study utilizes RStudio and CiteSpace software to comprehensively analyze the research trends and progress of magnetic biochar in wastewater treatment. The analysis of bibliometrics is performed on 551 relevant papers retrieved from the Web of Science, spanning the period between 2011 and 2022. The most influential countries, institutions, journals, disciplinary distribution, and top 10 authors and papers in this field have been identified. The latest dataset has been used for keyword clustering and burst analysis. The results indicated that: (1) Bin Gao is the most influential author in this field, and high-level journals such as Bioresource Technology are more inclined to publish articles in the field of magnetic biochar. (2) Research in this field has predominantly focused on the removal of heavy metals and organic compounds. Keyword burst analysis shows a shift in research direction towards the removal of complex organic pollutants recently. (3) For the future development of magnetic biochar, an environment-friendly approach, economic viability, and joint technology are the directions that need more exploration. Finally, this paper provides a summary of the various adsorption mechanisms of magnetic biochar and several common modification methods, aiming to assist scholars in their research endeavors.
Corn straw, a typical agricultural waste, was directly converted into hydrochar with a yield of 77.56% by hydrothermal carbonization at 140–230 °C for 2 h with a solid–liquid ratio of 1:20. The morphology and surface properties were characterized by elemental analysis, specific surface area and pore size analysis and Fourier transform infrared spectroscopy. The results showed that with the increase of hydrothermal reaction temperature, some physical and chemical properties such as the increase of hydrocarbon content, crystallinity, and specific surface area of hydrochar changed significantly. A series of chemical reactions such as dehydration, decarboxylation, and aromatization occurred in the hydrothermal carbonization process so that the prepared hydrochar had rich oxygen-containing functional groups (-HO, C-O-C, C=O) and unique porous structure made the hydrochar prepared at 170 °C had the best removal effect on Cd2+ in solution (5.84 mg/g). These specific conditions could remove Cd2+ and greatly improve the adsorption performance. The pseudo-second-order kinetic model and Freundlich isotherm model could better describe the adsorption behavior of Cd2+. Therefore, corn straw hydrochar as a potential adsorbent for removing Cd2+ from water.
To enhance the efficient development of geothermal energy, this study investigates the heat transfer enhancement mechanisms in medium-depth coaxial underground heat exchangers (CUHEs) integrated with corrugated fins, using computational fluid dynamics (CFD) simulations. Nine distinct corrugated fin geometries were modeled, and the streamlines, velocity fields, temperature fields, and turbulent kinetic energy were analyzed across Reynolds numbers (Re) ranging from 12,000 to 42,000. The results demonstrate that corrugated fins significantly promote fluid turbulence and mixing, thereby augmenting convective heat transfer. Compared to smooth inner tubes, the Nusselt number (Nu) is enhanced by a factor of 1.43–2.19, while the friction factor (f) increases by a factor of 2.94–6.79. The performance evaluation criterion (PEC) improves with increasing fin width and decreasing fin spacing. The optimal configuration, featuring a fin width of 15 mm, a spacing of 60 mm, and a thickness of 15 mm, achieves a maximum PEC value of 1.34 at Re = 12,000, indicating a substantial improvement in heat transfer performance within acceptable pressure drop limits. This research innovatively explores the performance enhancement of CUHEs at high Re, systematically elucidates the influence of geometric parameters on heat transfer and flow resistance, and employs the PEC index to optimize the structural design. This provides significant theoretical support for the efficient engineering application of CUHEs in geothermal utilization.
28 September 2019 in International Journal of Heat and Technology