Different fluid compositions have been considered as heat transfer fluids (HTF) for concentrating solar power (CSP) applications. In linear focusing CSP systems synthetic oils are prevalently employed; more recently, the use of molten salt mixtures in linear focusing CSP systems has been proposed too. This paper presents a comparative assessment of thermal oils and five four nitrate/nitrite mixtures, among the ones mostly employed or proposed so far for CSP applications. The typical medium-size CSP plant (50 MWe) operating with synthetic oil as HTF and the “solar salt” as TES was considered as a benchmark. In the first part of the paper, physical properties and operation ranges of different HTFs are reviewed; corrosion and environmental issues are highlighted too. Besides an extensive review of HTFs based on data available from the open literature, the authors report their own obtained experimental data needed to thoroughly compare different solutions. In the second part of the paper, the impact of the different HTF options on the design and operation of CSP plants are analyzed from techno-economic perspectives.

Molten salts eutectics are promising candidates as phase change materials (PCMs) for thermal storage applications, especially considering the possibility to store and release heat at high temperatures. Although many compounds have been proposed for this purpose in the scientific literature, very few data are available regarding actual applications. In particular, there is a lack of information concerning thermal storage at temperatures around 600 °C, necessary for the coupling with a highly efficient Rankine cycle powered by concentrated solar power (CSP) plants. In this contest, the present work deals with a thermophysical behavior investigation of a storage heat exchanger containing a cost-effective and safe ternary eutectic, consisting of sodium chloride, potassium chloride, and sodium carbonate. This material was preliminarily and properly selected and characterized to comply with the necessary melting temperature and latent enthalpy. Then, an indirect heat exchanger was considered for the simulation, assuming aluminum capsules to confine the PCM, thus obtaining the maximum possible heat exchange surface and air at 5 bar as heat transfer fluid (HTF). The modelling was carried out setting the inlet and outlet air temperatures at, respectively, 290 °C and 550 °C, obtaining a realistic storage efficiency of around 0.6. Finally, a conservative investment cost was estimated for the storage system, demonstrating a real possible economic benefit in using these types of materials and heat exchange geometries, with the results varying, according to possible manufacturing prices, in a range from 25 to 40 EUR/kWh.

Chemical systems for thermal energy storage are promising routes to overcome the issue of solar irradiation discontinuity, helping to improve the cost-effectiveness and dispatchability of this technology. The present work is concerned with the simulation of a configuration based on an indirect-packed bed heat exchanger, for which few experimental and modelling data are available about practical applications. Since air shows advantages both as a reactant and heat transfer fluid, the modelling was performed considering a redox oxide based system, and, for this purpose, it was considered a pelletized aluminum/manganese spinel. A symmetrical configuration was selected and the calculation was carried out considering a heat duty of 125 MWth and a storage period of 8 h. Firstly, the heat exchanger was sized considering the mass and energy balances for the discharging step, and, subsequently, air inlet temperature and mass flow were determined for the charging step. The system performances were then modelled as a function of the heat exchanger length and the charging and discharging time, by solving the relative 1D Navier-Stokes equations. Despite limitations in the global heat exchange efficiency, resulting in an oversize of the storage system, the results showed a good storage efficiency of about 0.7.