This research paper aims to fabricate flexible PVA/Cs/TiO₂ nanocomposite films consisting of polyvinyl alcohol (PVA), chitosan (Cs), and titanium oxide (TiO₂) for application in energy storage devices. The samples were analyzed using X-ray diffraction (XRD), atomic force microscope (AFM), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and energy dispersive X-ray (EDX) techniques. The impact of TiO₂ on the electrical impedance, conductivity, permittivity, and energy efficiency of the PVA/Cs was determined in a frequency range of 100 Hz to 5 GHz. The XRD, FTIR, and EDX results showed the successful fabrications of the PVA/Cs/TiO₂. The SEM and AFM images illustrated that the TiO₂ was loaded and distributed homogenously in PVA/Cs chains. In addition, the electrical conductivity was enhanced from 0.04 × 10⁻⁷ S.cm⁻¹ of PVA/Cs to 0.25 × 10⁻⁷ S.cm⁻¹ and 5.75 × 10⁻⁷ S.cm⁻¹, respectively, for the composite PVA/Cs/0.01TiO₂ and PVA/Cs/0.1TiO₂, and the dielectric constant grew from 2.46 for PVA/Cs to 7.38 and 11.93, respectively. These results revealed that modifications were made to the produced films, paving the way for using the composite PVA/Cs/TiO₂ films in different energy applications, such as electronic circuits and supercapacitors.

Iron-doped Zinc oxide nanoparticles were produced by the sol-gel combustion method. This study aims to see how iron doping affects the structural, optical, and photocatalytic characteristics of ZnO composites. XRD examined all samples to detect the structural properties and proved that all active materials are a single hexagonal phase. The morphology and particle size were investigated by TEM. Computational Density functional theory (DFT) calculation of the band structure, density of state, and charge distributions for ZnO were investigated in comparison with ZnO dope iron. We reported the application results of ZnO doped Fe for Methylene blue dye removal under photocatalytic degradation effect. The iron concentrations affect the active material’s band gap, producing higher photocatalytic performance. The acquired results could be employed to enhance the photocatalytic properties of ZnO.

The current contribution goal is to measure the distribution of the radionuclide within the exposed rock units of southwestern Sinai, Seih-Sidri area, and assess the radiological risk. Gneisses, older granites, younger gabbro, younger granites, and post granitic dikes (pegmatites) are the main rock units copout in the target area. Radioactivity, as well as radiological implications, were investigated for forty-three samples from gneisses (seven hornblende biotite gneiss and seven biotite gneiss), older granites (fourteen samples), and younger granites (fifteen samples of syenogranites) using NaI (Tl) scintillation detector. External and internal hazard index (H_ex, H_in), internal and external level indices (Iα, Iγ), absorbed dose rates in the air (D), the annual effective dose equivalent (AED), radium equivalent activity (Ra_eq), annual gonadal dose (AGDE), excess lifetime cancer risk (ELCR), and the value of Upper Continental Core ²³²Th/²³⁸U mass fractions were determined from the obtained values of ²³⁸U, ²³²Th and ⁴⁰K for the examined rocks of Seih-Sidri area. The average ²³⁸U mg/kg in hornblende biotite gneiss and biotite gneiss, older granites, and syenogranites is 2.3, 2.1, 2.7, and 8.4 mg/kg, respectively, reflecting a relatively higher concentration of uranium content in syenogranites. The results suggest that using these materials may pose risks to one’s radiological health.

Radiation shielding is crucial in many types of medical, industrial, and nuclear facilities due to the widespread usage of radioactive isotopes. In this research, we examine the impact of tellurite 65TeO₂–(35-x)V₂O₅-xSm₂O₃ glasses, where x ranges from 0.1 to 5 mol%, for its nuclear security and radiation shielding versus gamma attenuation capabilities. For gamma, the effect that the systematic replacement of Sm₂O₃ with V₂O₅ has on the shielding qualities was dissected in great depth. In addition, comparative research was carried out using the most recent borate glasses and the typical shielding materials considered the industry standard. In this study, we utilized the FLUKA algorithm and the FLAIR graphical interface to calculate the attenuation coefficients of glass compositions in the 65TeO₂–(35-x)V₂O₅-xSm₂O₃system. The gamma energies of 0.356, 0.662, 1.332, and 2.614 MeV, commonly used in gamma shielding investigations, were selected as the radiation source. A comparison between the simulation results by FLUKA and theoretical calculations for mass attenuation coefficients demonstrated excellent agreement, confirming the reliability and accuracy of the FLUKA simulation method. The findings of the current research point to the fact that the TVS5 sample has the highest G_MAC and lowest G_HVL and G_MFP, among other glasses. This points to the possibility that the TVS5 sample might be used in radiation shielding activities, which would result in increased nuclear safety.

Solar cells in superstrate arrangement need a protective cover glass as one of its main components. The effectiveness of these cells is determined by the cover glass’s low weight, radiation resistance, optical clarity, and structural integrity. Damage to the cell covers brought on by exposure to UV irradiation and energetic radiation is thought to be the root cause of the ongoing issue of a reduction in the amount of electricity that can be generated by solar panels installed on spacecraft. Lead-free glasses made of xBi₂O₃–(40 − x)CaO-60P₂O₅ (x = 5, 10, 15, 20, 25, and 30 mol%) were created using the usual approach of melting at a high temperature. The amorphous nature of the glass samples was confirmed using X-ray diffraction. At energies of 81, 238, 356, 662, 911, 1173, 1332, and 2614 keV, the impact of various chemical compositions on gamma shielding in a phospho-bismuth glass structure was measured. The evaluation of gamma shielding revealed that the results of the mass attenuation coefficient of glasses increase as the Bi₂O₃ content increases but decrease as the photon energy increases. As a result of the study conducted on the radiation-deflecting properties of ternary glass, a lead-free low-melting phosphate glass that exhibited outstanding overall performance was developed, and the optimal composition of a glass sample was identified. The 60P₂O₅–30Bi₂O₃–10CaO glass combination is a viable option for use in radiation shielding that does not include lead.