The Nangqen and Qamdo (NQ-QD) basins in China have very rich geothermal and brine resources. The origin and spatiotemporal evolutionary processes of its hot and saline springs however remain unclear. Geochemical and isotopic (¹⁸O, ²H, ³H) studies have therefore been conducted on the water from the geothermal and saline springs in the NQ-QD Basin. All saline springs in the study area are of the Na-Cl geochemical type while geothermal waters show different geochemical types. The oxygen and hydrogen isotopic compositions of the springs in the NQ-QD Basin are primarily controlled by meteoric water or ice-snow melt water and are influenced by rock-water interactions. It is found that the saline springs in the study area are derived from the dissolution of halite and sulfate that occur in the tertiary Gongjue red bed, while the hot springs in the QD Basin are greatly influenced by the dissolution of carbonatites and sulfates from the Bolila (T₃b) and Huakaizuo (J₂h) formations. Results from silica geothermometry and a silicon-enthalpy hybrid model indicate that the apparent reservoir temperatures and reservoir temperatures for the hot springs in the QD Basin range from 57130C to75214C, respectively. Deuterium analysis indicates that most of the hot springs are recently recharged rain water. Furthermore, the saline springs have a weaker groundwater regeneration capacity than the hot springs. Tritium data shows that the ranges of calculated residence times for springs in this study are 25 to 55 years, and that there is a likelihood that hot springs in the QD Basin originated from two different hydrothermal systems. The geochemical characteristics of the NQ-QD springs are similar to those of the Lanping-Simao Basin, indicating similar solute sources. Thus, the use of water isotope analyses coupled with hydrogeochemistry proves to be an effective tool to determine the origin and spatiotemporal evolution of the NQ-QD spring waters.

The Reshui area, located to the northeast of the Qinghai–Tibet Plateau, exhibits complex geological conditions, well-developed structures, and strong hydrothermal activities. The distribution of hot springs within this area is mainly controlled by faults. In this paper, five hot springs from the area were taken as the research object. We comprehensively studied the geochemical characteristics and genetic mechanism of the geothermal water by conducting a field investigation, hydrogeochemistry and environmental isotopic analysis (⁸⁷Sr/⁸⁶Sr, δ²H, δ¹⁸O, ³H). The surface temperature of the geothermal water ranges from 84 to 91 °C. The geothermal water in the area exhibits a pH value ranging between 8.26 and 8.45, with a total dissolved solids’ (TDS) concentration falling between 2924 and 3140 mg/L, indicating a weakly alkaline saline nature. It falls into the hydrochemical type CI-Na and contains a relatively high content of trace components such as Li, Sr, B, Br, etc., which are of certain developmental value. Ion ratio analysis and strontium isotope characteristics show that the dissolution of evaporite minerals and carbonate minerals serves as a hot spring for the main source of solutes. Hydrogen and oxygen stable isotope characteristics findings indicate that the geothermal water is primarily recharged via atmospheric precipitation. Moreover, the tritium isotopic data suggest that the geothermal water is a mixture of both recent water and ancient water. Moreover, the recharge elevation is estimated to be between 6151 and 6255 m. and the recharge area is located in the Kunlun Mountains around the study area. The mixing ratio of cold water, calculated using the silicon enthalpy equation, is approximately 65% to 70%. Based on the heat storage temperature calculated using the silicon enthalpy equation and the corrected quartz geothermal temperature scale, we infer that the heat storage temperature of geothermal water in the area ranges from 234.4 to 247.8 °C, with a circulation depth between 7385 and 7816 m. The research results are highly valuable in improving the research level concerning the genesis of high-temperature geothermal water in Reshui areas and provide essential theoretical support for the rational development and protection of geothermal resources in the area.

This paper discusses the origin and evolution of saline springs in north and central Laos, based on chemical and stable isotopes (δD, δ¹⁸O, δ¹¹B, and δ³⁷Cl). All the saline springs in this study are of the Na–Cl geochemical type. The geochemical and water isotope values suggest that the saline springs in this study are mainly derived from meteoric water and/or ice and snow melt from the surrounding mountains and that they also experienced strong evaporation and intense rock–water interactions. The ionic ratios, characteristic coefficients, ternary Ca–SO₄–HCO₃ phase diagrams, and saturation indices of minerals show that the dissolution of halite, sulfate, and carbonate rocks may be the solute sources for saline springs in this study, whereas the underground brines in the Thakhek potash mining area are geochemically influenced by the dissolution of carnallite and sylvite. The global geothermal δ¹¹B–Cl/B relationship and δ¹¹B values (5.50 to 36.01‰) of saline springs suggest a continental origin of B. This B is most likely derived from marine carbonate rocks and marine evaporates (gypsum and halite) of the late Cretaceous, which is similar to the saline springs of the Nangqen–Qamdo–Simao Salt Basin. The δ³⁷Cl value (−0.12 to +0.79) and the Cl/Br ratio (4076 to 9853) show that dissolution of late cretaceous marine halite layers, atmospheric precipitation, and water–rock interactions between volcanic rocks, mudstones, and sandstone can restrict the δ³⁷Cl values in saline springs. Results from silica geothermometry and multi–mineral equilibrium diagrams indicate that the reservoir temperatures for the saline springs range from 87–137 °C and experience deep circulation. Hydrochemical characteristic coefficients suggest that saline springs in the Muang Say basin may have leached sylvinite and carnallite and that the potash exploration prospect in this area is relatively good.

The Balun Mahai Basin (BLMH), located in the northern Qaidam Basin (QB), is endowed with substantial brine resources; however, the genetic mechanisms and potential of these brine resources remain inadequately understood. This study investigated the intercrystalline brine (inter-brine) in BLMH, performing a comprehensive geochemical analysis of elemental compositions and H-O-Sr isotopes. It evaluated the water source, solute origin, evolutionary process, and genetic model associated with this brine. Moreover, a mass balance equation based on the ⁸⁷Sr/⁸⁶Sr isotopic ratio was developed to quantitatively evaluate the contributions of Ca-Cl water and river water to the inter-brine in the study area. The results suggest that the hydrochemical type of inter-brine in the north part of BLMH is Cl-SO₄-type and in the south part is Ca-Cl-type. The solutes in brine are mainly derived from the dissolution of minerals such as halite, sylvite, and gypsum. The hydrochemical process of brine is controlled by evaporation concentration, water–rock interaction, and ion exchange interaction. Hydrogen and oxygen isotopes suggest that the inter-brine originates from atmospheric precipitation or ice melt water and has experienced intense evaporation concentration and water–rock interaction. The strontium isotopes suggest that the inter-brine was affected by the recharge and mixing of Ca-Cl water and river water, which controlled the spatial distribution and formation of brine hydrochemical types. The analysis of ionic ratios suggest that the inter-brine is derived from salt dissolution and filtration, characterized by poor sealing and short sealing time in the salt-bearing formation. The differences in hydrochemical types and spatial distribution between the north and the south are fundamentally related to the replenishment and mixing of these two sources, which can be summarized as mixed origin model of “dissolution and filtration replenishment + deep replenishment” in BLMH.

The claystone in the Guide area of the Qaidam Basin on the northeastern margin of the Qinghai-Xizang Plateau contains lithium resources. This paper adopts geochemical and isotopic geochemical approaches to analyze the paleoenvironment, tectonic setting, sediment provenance, weathering processes, and lithium sources of the lithium-bearing claystones in the study area, and summarizes the genetic mechanisms of the lithium-bearing claystones. The results indicate that the claystone is dominated by illite and chlorite in mineral composition, with lithium primarily hosted in illite and kaolinite. The paleo-sedimentary aqueous conditions of the claystone correspond to a weakly oxidizing-weakly reducing, brackish water environment, under a semi-arid to semi-humid paleoclimate. Meanwhile, weakly oxidizing-weakly reducing, freshwater, and humid sedimentary environments are more favorable for the formation of lithium-bearing minerals, as evidenced by the highest lithium content in the clay. The source rocks of lithium-bearing clays in the study area were subject to the tectonic setting of the island arc-continental margin transition. Their provenance is dominated by felsic igneous rocks, with minor contributions from intermediate igneous rocks and recycled sedimentary materials. Weathering conditions of the lithium-bearing claystones in the study area indicate that their source rocks experienced weak to moderate weathering, and a certain degree of potassium metasomatism may have occurred during diagenesis. Lithium isotope analyses reveal that lithium in the clays is primarily derived from lithium supplied by sedimentary-stage water bodies and deep-seated hydrothermal fluids. Lithium isotope analysis shows that the δ ⁷ Li values of lithium in the clay range from 3.67‰ to 8.27‰, with an average of 5.7‰, it indicates that the lithium in the clay of the study area may originate from deep hydrothermal fluids and sedimentary detrital materials.