Spatial heterodyne Raman spectroscopy is a spectroscopic detection technique that is particularly suitable for Raman measurements. The spectral range of traditional spatial heterodyne Raman spectrometer (SHRS) is limited by its spectral resolution and the number of detector elements. We propose an SHRS with an echelle-mirror structure that employs multiple diffraction orders to achieve a broad spectral coverage and high spectral resolution simultaneously. This SHRS is used to obtain the Raman spectra of organic liquids, inorganic solid targets, and mixed targets. Observations of aqueous solutions, and minerals are presented. In addition, anti-Stokes Raman shifts are also presented. The proposed SHRS technique shows good performance for broadband, high-resolution Raman measurements.

The designs of 300 mm ruling engine producing gratings and echelles under interferometric control (CIOMP-2) are presented. A new ruling-tool carriage system and its driving mechanism—which are easy to manufacture—are proposed. A new blank carriage system, controlled by a dual-frequency laser interferometer and a piezoelectric actuator, is designed. The CIOMP-2 ruling engine can now rule grating blanks with dimensions up to $300\mathrm{mm}\times 300\mathrm{mm}$, and mainly rules gratings with grating constants between 10 and $2400\text{lines}/\mathrm{mm}$. The wavelength range of CIOMP-2 gratings is from ultraviolet to mid-infrared wavelengths. Experiments show that the new ruling-tool carriage system works well and stability of motion is improved with the help of a flexure-hinge structure, and the threefold standard deviation values of the blank carriage positioning errors are less than $\sim 5\mathrm{nm}$. For $600\mathrm{line}/\mathrm{mm}$ gratings (diffraction order $m=-1$), the scatter intensities and ghosts reach ${10}^{-5}$ of the maximum intensity. The scatter intensities and ghost of gratings ruled with CIOMP-2 are low, and no Rowland ghosts are visible. The gratings ruled by CIOMP-2 have high diffraction efficiency and resolving power. CIOMP-2 can also produce varied-line-space, bend-line, and aberration-reducing gratings and echelles.

A field-widened spatial heterodyne Raman spectrometer with a mosaic grating structure is developed for the simultaneous sensitivity enhancement and broadband transmission Raman measurements. We optimize the etendue to maximize the signals collected from the samples by using field-widening prisms and employ two mosaic gratings to achieve broadband operation, covering 5638 cm⁻¹ with 2.865 cm⁻¹ spectral resolution. The signal-to-noise ratios are improved by a factor of more than 11 and show a good stability and fair repeatability. We investigate the effects of the sample thickness and outer layer depth and observe liquids, solids, mixed targets, and anti-Stokes shifts. The instrument exhibits good performance for wide-field, high-resolution broadband transmission Raman measurements.

This work presents a method that can automatically estimate and remove varying continuous background emission for low-cost laser-induced breakdown spectroscopy (LIBS) without intensified CCD. The algorithm finds all third-order minima points in spectra and uses these points to partition the spectra into multiple subintervals. The mean value is then used as a threshold to select the effective points for the second-order minima in each subinterval. Finally, a linear interpolation method is used to realize extension of these effective points and complete fitting of the background using polynomials. Using simulated and real LIBS spectra with different complexities examine the validity of proposed algorithm. Additionally, five elements of five standard cast iron alloy samples are calibrated and improved very well after background removal. The results successfully prove the validity of the background correction algorithm.