A simple and facile strategy has been developed for synthesis of nanomaterials viapolymerization in high concentration; multiple morphologies can be created and tuned just by variation of the feed ratio and reaction conditions.

A novel strategy for preparation of multiple nanostructural materials, which is the creation of such materials directly from controlled radical dispersion polymerization in one pot, has been developed. In the formation of polymeric nanomaterials, the chain length ratio of the hydrophobic to hydrophilic blocks is altered continuously, which induces two phase transitions, phase separation to form spherical micelles and re-organization of the resulting spheres to yield multiple morphologies including nanorods, nanotubes, vesicles and doughnuts. This is quite different from self-assembly of the block copolymer in a selective solvent, where nature and solubility parameter of the solvents are changed. In the reversible addition-fragmentation chain transfer (RAFT) polymerization of styrene in methanol using poly(4-vinylpyridine) as macro RAFT agent, the resultant polymeric nanomaterials with various morphologies coexisted generally, however, uniform nanowires and vesicles could be prepared by appropriately selecting concentration of monomer and feed ratio, as well as by strict control of reaction conditions. One advantage of this strategy is that the nanomaterials with a concentration as high as 0.5 g mL⁻¹ can be achieved, this provides possibility for studying extensive applications of the various nanomaterials.

The introduction of main group elements into conjugated scaffolds is emerging as a key route to novel optoelectronic materials. Herein, an efficient and versatile way to synthesize polymerizable 9,10-azaboraphenanthrene (BNP)-containing monomers by aromaticity-driven ring expansion reactions between highly antiaromatic borafluorene and azides is reported, and the corresponding conjugated small molecules and polymers are developed as well. The BNP-containing small molecules and conjugated polymers showed good air/moisture stability and notable fluorescence properties. Addition of fluoride ions to the BNP-based small molecules and polymers induced a rapid change in the emission color from blue to green/yellow, respectively, accompanied by strong intensity changes. The conjugated polymers showed better ratiometric sensing performance than small molecules due to the exciton migration along the conjugated chains. Further experiments showed that the sensing process is fully reversible. The films prepared by solution-deposition of BNP-based compounds in the presence of polycaprolactone also showed good ratiometric sensing for fluoride ions.

Polymerization-induced self-assembly and re-organization (PISR) was used to prepare polymeric nanostructured materials with a variety of morphologies. Reversible addition-fragmentation chain transfer (RAFT) polymerization of styrene in a selective solvent, methanol, was carried out using cyanoisopropyl dithiobenzoate-terminated poly(2-dimethylaminoethyl methacrylate) (PDMAEMA-DBT) as the macro chain transfer agent and stabilizer for investigation of the factors influencing the formation of morphologies. Various morphologies, including spherical micelles, nanostrings, vesicles and large compound vesicles, with different shapes were obtained by changing the feed ratios and reaction conditions. The sequential morphologic transitions from spherical micelles to nanostrings, to vesicles and to large compound vesicles via increasing the chain length ratio of the hydrophobic block to the hydrophilic one in the same system were observed for the first time. This approach can be performed at a high concentration, thus it can be scaled up for the reproducible preparation of nanostructured materials in a relatively high volume.