The quantum confinement effect and interesting optical properties of cesium lead halide (CsPbX ₃ ; X = Cl, Br, I) perovskite quantum dots (QDs) and nanocrystals (NCs) have given a new horizon to lighting and photonic applications. Given the exponential rate at which scientific results on CsPbX ₃ NCs are published in the last few years, it can be expected that the research in CsPbX ₃ NCs will further receive increasing scientific interests in the near future and possibly lead to great commercial opportunities to realize these materials based practical applications. With the rapid progress in the single-photon emitting CsPbX ₃ QDs and NCs, practical applications of the quantum technologies such as single-photon emitting light-emitting diode, quantum lasers, quantum computing might soon be possible. But to reach at cutting edge of stable perovskite QDs/NCs, the study of fundamental insight and theoretical aspects of crystal design is yet insufficient. Even more, it has aroused many unanswered questions related to the stability, optical and electronic properties of the CsPbX ₃ QDs. Aim of the present review is to illustrate didactically a precise study of recent progress in the synthesis, properties and applications of CsPbX ₃ QDs and NCs. Critical issues that currently restrict the applicability of these QDs will be identified and advanced methodologies currently in the developing queue, to overcome the roadblock, will be presented. And finally, the prospects for future directions will be provided.

A visible light active Ag-decorated BiVO ₄ -BiOBr dual heterojunction photocatalyst was prepared using a facile hydrothermal method, followed by the photodeposition of Ag. The photocatalytic activity of the synthesized samples was investigated by monitoring the change in malachite green (MG) concentration upon visible light irradiation. The synthesized sample was highly effective for the degradation of non-biodegradable MG. The enhanced activity observed was ascribed to the efficient separation and transfer of charge carriers across the dual heterojunction structure as verified by photoluminescence measurements. The removal of MG was primarily initiated by hydroxyl radicals and holes based on scavenger’s effect. To gain insight into the degradation mechanism, both high performance liquid chromatography and high resolution-quantitative time of flight, electrospray ionization mass spectrometry measurements during the degradation process were carried out. The degradation primarily followed the hydroxylation and N-demethylation process. A possible reaction pathway is proposed on the basis of all the information obtained under various experimental conditions.

The high-temperature heat treatment of electroless nickel–phosphorus (Ni-P) coatings in an air environment, and its consequences have scarcely been investigated. This work investigated tribological characteristics of the high-temperature, heat-treated, electroless Ni-P coatings on steel substrates with low-, mid-, and high-phosphorus content for which the average phosphorus content was 2.4 wt.%, 7.1 wt.%, and 10.3 wt.%, respectively. X-ray fluorescence and energy dispersive spectroscopy were implemented to determine the phosphorus content of the coatings. The oxidation of Ni and the formation of the NiO layer on the coating surface was confirmed by the X-ray diffraction technique. A reciprocating sliding method on a ball-on-flat system was utilized to evaluate the coating’s friction and wear behavior. Among the coatings with varying phosphorus content, a high hardness of 1086 HV was found for high-phosphorus coating when heat-treated at 400 °C in an air environment, and that was decreased to 691 HV when heat-treated at 650 °C. The oxidation of nickel in the electroless Ni-P coating occurred when heat-treated at 400 °C in an air environment, and this phenomenon was increased more when the temperature was increased to 650 °C. The characteristics of the NiO layer that formed on the surface of the heat-treated electroless Ni-P coating were influenced by the concentration of phosphorus, which caused different colors of NiO to be seen on the Ni-P coating surface. A greenish black NiO layer on the low-phosphorus and black NiO layer on the mid- and high-phosphorus Ni-P coating was developed during heat treatment at 650 °C in an air atmosphere. The adhesion and tribological characteristics of the Ni-P coatings were affected by the NiO layer developed on the heat-treated Ni-P coating surfaces. The Ni-P coatings with mid- and high-phosphorus content showed enhanced wear-resistance characteristics when they underwent heat treatment in an air atmosphere at the high temperature of 650 °C. The wear volume obtained for as-plated mid-phosphorus and high-phosphorus Ni-P coatings was 0.111 mm³ and 0.128 mm³, respectively, and that was reduced to 0.031 mm³ and 0.051 mm³, respectively, after the high-temperature heat treatment.

Yb ³⁺ and Er ³⁺ doped YVO ₄ (Yb ³⁺ /Er ³⁺ :YVO ₄ ) nanoparticles with highly efficient near-infrared to visible upconversion properties have been synthesized by microwave hydrothermal process. Uniform-sized Yb ³⁺ /Er ³⁺ :YVO ₄ nanoparticles were synthesized within 1 h at 140 °C which is relatively faster than the conventional hydrothermal process. Under 980 nm laser excitation, strong green and less strong red emissions are observed which are attributed to ² H _11/2 , ⁴ S _3/2 to ⁴ I _15/2 and ⁴ F _9/2 to ⁴ I _15/2 transitions of Er ³⁺ respectively. The emission intensity is found to depend strongly on the concentration of Yb ³⁺ . The quadratic dependence of upconversion intensity on the excitation power indicates that the upconversion process is governed by two-photon absorption process.

Nanomaterials are the subject of extensive investigations due to their applications in medicine, multimodal imaging, volumetric displays, and photonics. Here, lanthanide-doped bismuth vanadate (BiVO ₄ ) upconverting nanoparticles (UCNPs) have been reported. The nanoparticles have been synthesized by a microwave hydrothermal method. As-synthesized nanoparticles are highly crystalline in the tetragonal zircon phase with particles about 200 nm in size. Under 980 nm excitation, intense multicolor visible and near-infrared upconversion emissions are observed. Moreover, broadband infrared downshifting emissions are also observed. Time-resolved emission measurements have been carried out to investigate the involved upconversion and energy transfer mechanism. The BiVO ₄ -based UCNPs may provide a new class of nanomaterials for multifunctional applications.