This work aims at reviewing the most impactful results obtained on the development of Cu-based photocathodes. The need of a sustainable exploitation of renewable energy sources and the parallel request of reducing pollutant emissions in airborne streams and in waters call for new technologies based on the use of efficient, abundant, low-toxicity and low-cost materials. Photoelectrochemical devices that adopts abundant element-based photoelectrodes might respond to these requests being an enabling technology for the direct use of sunlight to the production of energy fuels form water electrolysis (H₂) and CO₂ reduction (to alcohols, light hydrocarbons), as well as for the degradation of pollutants. This review analyses the physical chemical properties of Cu₂O (and CuO) and the possible strategies to tune them (doping, lattice strain). Combining Cu with other elements in multinary oxides or in composite photoelectrodes is also discussed in detail. Finally, a short overview on the possible applications of these materials is presented.

Wastewater globally is a significant concern for environmental health and for the sustainable management of water resources. Catalysed based advanced oxidation processes (AOP), as a relatively low operation cost and high removal efficiency of pollutants method, has a promising potential to treat the wastewater. Among the numerous catalysts, Layered Double Hydroxides (LDHs) stands out for lamellar structure, high charge density, and tuneable properties. Meanwhile, oxygen vacancies engineering could modulate the electronic properties of materials and create active centres to regulate the poor charge transfer capability of LDHs. In this regard, this review is focused on how to create and confirm the oxygen vacancies, as well as the applications of the wastewater treatment from different AOPs. It starts with the synthesized of oxygen vacancies via chemical reduction method, plasma etching method, hydrothermal treatment method, ion doping strategy. Followed by the description of characterization methods, including EPR, XPS, XAS, Raman. Finally, the role of oxygen vacancies in LDHs for contaminant removal across various systems, including photocatalysis, electrocatalysis, Fenton reactions, and sulfate radical-based processes, was thoroughly examined and analyzed.

Oxidative cleavage of carbon-carbon double bonds often requires hazardous reagents and demanding conditions. In this study, we report a photocatalytic oxidative cleavage of alkenes using benign carbon dioxide (CO ₂ ) as an oxygen donor, producing ketones or carboxylic acids at atmospheric pressure and room temperature. A robust iron-based heterogeneous photocatalyst facilitates oxygen transfer to form an epoxide intermediate that subsequently undergoes ring opening and carbon-carbon bond cleavage to yield the oxidative products with high selectivity. Comprehensive mechanistic studies combine time-resolved spectroscopy, isotope labeling, and in situ spectroscopic analyses with advanced quantum mechanical simulations. These results uncover fundamental principles of oxygen transfer from CO ₂ under photocatalytic conditions, offering a sustainable platform for light-driven oxidative transformations.

Boosting the hydrogen evolution reaction in an alkaline environment by enhancing the activity of Pd nanoparticles exploiting the unique redox activity of ZrO ₂ .