In this study, the production of stereocomplex PLA formulations (sc-PLA) by compounding and subsequent injection moulding at different mould temperatures was investigated. Several selective nucleating agents were identified and compounded with different poly(L-lactide)/poly(D-lactide) (PLLA/PDLA) ratios on a co-rotating twin screw extruder. The effect of nucleating agents (NA) on the crystallisation behaviour of the compound was systematically investigated by DSC analysis. The crystallisation behaviour of NA-21 (aluminium complex of a phosphoric ester), also in combination with talc, under cooling rates of up to 70 K/min was analysed. The wide-angle X-ray diffraction (WAXD) results showed a complete stereocomplex (sc) crystal formation on all specimens containing NA-21 even at the highest cooling rates. The thermo-mechanical testing of sc-PLA shows a Young’s modulus of approx. 3 GPa, yield stress of 30–40 MPa, elongation of 1%, and a heat deflection temperature (HDT-B) up to 180 °C. Processing sc-PLA exclusively via the processing route of compounding and injection moulding will open new areas of application for PLA at higher temperatures.
Foreword The International Conference on Gears in Garching near Munich, Germany, is an established platform for researchers on and manufacturers of gears and transmission systems. At the 10th issue of the conference in September of 2023, gear experts discussed the latest developments and research results from the powertrain industry and academia. Given the increasing challenges of climate change and its impacts, acting in compliance with the UN Sustainable Development Goals is mandatory for all engineers today. Gear engineers must consider these objectives in their research and development activities and provide solutions that meet the technical requirements and contribute to achieving the UN goals. Greenhouse gas (GHG) emission is a primary driver for climate change. Reducing GHG emissions should be an urgent action for the combat against climate change. Therefore, the research on efficiency is assigned a key role. Several contributions in this report discuss the possibilities for further improvement in efficiency from different points of view, like gear design or lubrication. Other subjects of the conferences are Responsible Consumption and Production. H...