Three−dimensional (3D) graphene with novel nano−architectures exhibits many excellent properties and is promising for energy storage and conversion applications. Herein, a new strategy based on the fluidized bed chemical vapor deposition (FB−CVD) process was proposed to prepare 3D graphene networks (3DGNs) with various nano−architectures. Specially designed SiC−C@graphene core/shell nanoparticles were prepared taking the advantages of the FB−CVD system, and 3DGNs with hierarchical nanostructures were obtained after removing the SiC core. The 3DGNs performed well as electrodes of lithium–sulfur batteries. The C–S cathode showed good rate performance at the current density of 0.1–2.0 C, and an initial discharge capacity of 790 mAhg⁻¹ cathode was achieved at a current density of 0.2 C. The Li−S batteries showed stabilized coulombic efficiency as high as 94% and excellent cyclic performance with an ultra low cyclic fading rate of 0.075% for the initial 280 cycles at a current density of 1.0 C. The improved electrochemical performance was ascribed to the enhanced conductivity by the connective graphene networks and the weakened shuttle effect by the special outer graphene layers. Mass production of the products was realized by the continuous FB−CVD process, which opens up new perspectives for large scale application of 3D graphene materials.

Two-dimensional materials have shown great potential for applications in many research areas because of their unique structures, and many 2D materials have been investigated since graphene was discovered. Ultra-thin SiC layers with thicknesses of 8–10 nm and multi-layer SiC films were designed and fabricated in this study. First, the multi-layer SiC films were obtained by the chemical vapor deposition (CVD) method with the addition of boron elements. We found that boron additives showed novel effects in the CVD process. Boron can promote the formation and crystallization of SiC films at low temperatures (1100 °C), resulting in the separation of SiC films into multi-layers with thicknesses of several nanometers. In addition, a formation mechanism for the 2D SiC layers is proposed. The boron mostly aggregated spontaneously between the thin SiC layers. Photoluminescence spectroscopy results showed that the SiC films with multi-layer structures had different bandgaps to normal SiC films. The present work proposes a potential method for fabricating 2D SiC materials with convenient experimental parameters and shows the potential of 2D SiC materials for use in electronics.

Fluidized bed-chemical vapor deposition (FB-CVD) technology stands as a cross-cutting achievement of fluidized bed technology in chemical engineering and chemical vapor deposition (CVD) in materials science, finding applications in particle coating, granulation, and material preparation. As compared to conventional CVD technology, FB-CVD distinguishes itself through enhanced heat/mass transfer efficiency, achieving a uniform coating layer while maintaining low production costs. Given the related research on FB-CVD micro-nano particle coating, the mechanism of particle fluidization and chemical vapor deposition, and the difficulty of micro-nano particle agglomeration were summarized. The process intensification of micro-nano particle fluidization assisted by particle design and external force field, such as vibration field, magnetic field, and sound field, and micro-nano particle chemical vapor deposition coating were summarized. In particular, applications of FB-CVD micro-nano particle coating are introduced. Finally, the opportunities and challenges faced by FB-CVD micro-nano particle coating technology are discussed, and the development prospect of this technology is prospected. This review is beneficial for the researchers of the fluidization field, and also the particle coating technology.