We demonstrate that by a simple solvothermal treatment followed by carbonization, plastic waste can be turned into graphitic carbon nanosheets, with an excellent photothermal conversion efficiency (99%) that is capable of generating a high evaporation rate (1.50 L m−2 h−1 at 1 kW m−2) in a solar evaporator, and these are among the best values reported thus far.
Hybrid perovskites show piezoelectric properties due to polarization and centro-symmetry breaking of PbX6 pyramids (X = I-, Br-, Cl-). This study examines the piezoelectric response of quasi-2D perovskites using various barrier molecules: benzyl amine (BzA), phenylethyl amine (PEA), and butyl diamine (BuDA). Utilizing piezoelectric force microscopy measurements, we determine the piezoelectric coefficient (d33) where BuDA exhibits a substantial response with values of 147 pm V–1 for n = 5, better than the other quasi-2D and 3D perovskite counterparts. Density functional theory calculations reveal distorted bond angles in the PbBr6 pyramids for quasi-2D perovskites, enhancing symmetry breaking. Additionally, polarizabilities and dielectric constants, derived from ab initio many-body perturbation theory, are highest for BuDA, followed by PEA and BzA, aligning with experimental results. We demonstrate pressure sensor performance, emphasizing the quicker capacitance decay time of the quasi-2D perovskite based on BuDA. This research underscores the impact of perovskite dimensionality on piezoelectricity, paving the way for the development of sensitive and wide-ranging pressure sensors.
Rh and Pd metallic thin films were fabricated by atomic layer deposition using Rh(acac) 3 and Pd(hfac) 2 precursors, and only low-concentration ozone as co-reactant.
This review provides a comprehensive overview of the latest breakthrough in 2D material-decorated devices in soft robotics: working principles, manufacturing approaches, challenges and opportunities.