The review describes the status of the studies and the recent achievements in the field of photoalignment of liquid crystals. An update classification of photoaligning materials and exposure schemes, and analyzes of the relationship between the molecular structure of the materials and characteristics of LC alignment are provided. In addition, bulk mediated photoalignment and combination of photoalignment with other alignment methods are discussed. Along with traditional, recently proposed applications of the photoalignment technique are considered.
We report on random lasing in a disordered system in which the multiple scattering feedback mechanism can be switched from a three-dimensional random walk to a quasi-two-dimensional type of transport. The emission from this system is anisotropic, extraordinary polarized, and is controlled via an external electric field. The phenomenon is observed in dye-doped polymer dispersed liquid crystals and makes use of the strong scattering anisotropies in these materials.
We describe a new aligning technique that yields uniform planar or tilted orientation of a nematic liquid crystal at different organic and inorganic substrates. The method is based on the oblique irradiation of an aligning substrate with a partially collimated flux of accelerated plasma. The sheet-like plasma flux is produced by an anode layer thruster with a race track geometry of the discharge channel. For liquid crystals with a positive dielectric anisotropy the technique produces two modes of uniform alignment: (1) with the easy axis in the incident plane of the plasma beam; (2) with the easy axis perpendicular to the plane of incidence. Mode 1 transforms into mode 2 as the irradiation dose increases. In mode 1, the pretilt angle can be controlled by changing the parameters of irradiation such as incidence angle, current density and particle energy. In mode 2, the pretilt angle is zero (planar alignment). The azimuthal anchoring coefficient is relatively weak (Wa∼10−6 J m−2) for the first type of alignment and strong (Wa≥10−4 J m−2, comparable to rubbed polymer substrates) for the second type. The two-mode alignment feature can be used to control alignment properties and to create alignment patterns. The method is free from the usual shortcomings of the traditional rubbing technique. We discuss possible mechanisms of the two-mode alignment and show that plasma-induced modifications of the substrate topography might be an important factor in liquid crystal alignment.
The irreversible electro-optical response (memory effect) of 'liquid crystal-aerosil' suspensions under the influence of an electric field is investigated. Thereby, the influence of the aerosil concentration on the efficiency of the memory effect is studied. The experimental results are discussed in the frame of a model where the filled nematic is considered as a system of aerosil agglomerates in a liquid crystal matrix stabilized by the forces of liquid crystal orientational elasticity.
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