A method based on a hydrothermal process was applied to obtain not only ultrafine but also well-dispersed CeO2 nanoparticles by the application of citric acid as a protective agent against particle growth. The well-defined crystallites have a narrow size distribution, and the mean size and BET specific surface area are 3.1 nm and 211 m2 g−1, respectively. A mixture of the condensation product of boric acid and 2,2′-iminodiethanol (diethanolamine) and cerium oxide nanoparticles has been found to yield turbostratic boron nitride (tBN) coatings on the cerium oxide surface after heating the mixture in a flow of ammonia. Formation of a tBN layer was identified using high-resolution electron microscopy and infrared and X-ray photoelectron spectroscopies. The surface tBN layer was found to be a few nanometres thick with a surface coverage of 51.2%. However, coating of cerium oxide with such a tBN layer is suitable both for whitening the colour whilst maintaining good ultraviolet absorption properties and for restraining the high oxidation activity of cerium oxide.
A novel Pt/CeO2–ZrO2–Bi2O3 catalyst was prepared to realize complete CO oxidation at room temperature or below even in the presence of moisture. Using this catalyst, a high CO oxidation activity and a high stability against moisture have been realized simultaneously.
Novel inorganic yellow pigments, Bi1−x−y−zCaxZnyLazVO4−(x+y)/2 (0.04 ≤ x ≤ 0.12; 0.01 ≤ y ≤ 0.05; 0.01 ≤ z ≤ 0.10) were synthesized as environmentally friendly inorganic materials, and their color properties were characterized. All the pigments exhibited brilliant yellow colors, and using the CIE L*a*b* system, the most vivid yellow hue was obtained for Bi0.85Ca0.08Zn0.02La0.05VO3.950 with a yellowness value (b*) of +93.5, which is much greater than that of a commercially available BiVO4 pigment (b* = +76.9). Since BiVO4 is an environmentally friendly inorganic yellow pigment, and Ca, Zn, and La are also nontoxic and safe elements, the Bi0.85Ca0.08Zn0.02La0.05VO3.950 pigment could be an effective alternative to conventional toxic yellow pigments.