Environmental pollution caused by heavy metal ions has become a major health problem across the world. In this study, a selective colorimetric sensor based on starch functionalized silver nanoparticles (St-Ag NPs) for rapid detection of Hg²⁺ in real samples was developed. The environmentally friendly green approach was utilized to synthesize starch functionalized silver nanoparticles (St-AgNPs). A multi-technique approach involving UV-Vis absorption spectroscopy, Fourier transform infrared (FT-IR), X-ray diffraction (XRD), and scanning electron microscope (SEM) was used for the characterization of St-Ag NPs. These starch functionalized AgNPs were tested for the detection of heavy metals at 25 °C. The screening process revealed clear changes in the AgNPs color and absorption intensity only in the presence of Hg²⁺ due to the redox reaction between Ag⁰ and Hg²⁺. The color and absorption intensity of nanoparticles remain unchanged in the presence of all the other tested metals ion. The proposed method has strong selectivity and sensitivity to Hg²⁺ ions, with a detection limit of 1 ppm revealed by UV-visible spectrophotometry. The proposed procedure was found to be successful for the detection of Hg²⁺ in real samples of tap water.

Water is a precious natural resource. Unfortunately, bodies of water become polluted by waste, such as untreated wastewater and detritus, along with oil spills, with minimum or no consideration for their limited capacity to renew themselves. Among these pollutants, dyes are harmful as they are persistent and not biodegradable in nature. The present study demonstrates the removal of crystal violet (CV), a toxic cationic dye, by using three systems: Peroxymonosulfate (PMS), UV-254 nm radiation and UV/P5MS. The effects of various parameters, such as the effects of the initial dose of crystal violet, initial concentration of PMS, pH, typical inorganic ions, etc., were also investigated. The effect of pH was investigated in the range of 1.92–12.07. Similarly, the effect of various anions such as NO₂^•−, HCO₃^•−, CO₃^•2−, SO₄^•2− and CH₃COO^•− was investigated for the degradation of target pollutants. The order of degradation of crystal violet was UV/PMS > PMS > UV with removal efficiencies of 97%, 76% and 42%, respectively, at reaction times of 60 min. The degradation of crystal violet was enhanced significantly at a pH range of 10.52–12.07. Electrical energy per order (EE/O) values for UV/PMS, PMS and UV were calculated to be 1.68, 3.62 and 48.96 KWh/m³/order, respectively. The addition of inorganic ions inhibited the removal of CV in the order of SO₄^•2− > NO₂^•− > HCO₃^•− > CO₃^•2− > CH₃COO^•−. Moreover, the kinetic studies on the degradation of CV by the UV-254 nm, PMS, and UV/PMS systems, were also carried out and found to follow pseudo-first-order kinetics. The study revealed that oxidation processes are most efficacious for the removal of organic dyes from wastewater.

In recent years, graphene has attracted the interest of many researchers working on LIB anode materials owing to its unique 2D structure, thermal stability, and fast electron transfer. In this work, RGO/Cu/Cu₂O nanocomposites were synthesized through a hydrothermal procedure. The as-prepared nanocomposites exhibited a high lithium storage capacity with improved cycling stability and great rate performance, i.e., the discharge capacity was 371.8 mAh/g after 100 cycles at a current density of 500 mA/g. These excellent properties were associated with the sheet structure symmetry of graphene enriched with the multifunctional Cu-Cu₂O component, which prevented aggregation and accommodated the volume changes of the anode material during the charge–discharge tests. The RGO/Cu/Cu₂O composite conferred to the LIB anode the ability to resist electrode cracking. The approach proposed in this paper can be also generalized for the synthesis of other carbon-based anode materials for LIBs.

The development of high-performance and stable solid-state lithium batteries (SSBs) is critical for advancing next-generation energy storage technologies. This study investigates LATP (Li_1.3Al_0.3Ti_1.7(PO₄)₃) coatings to enhance the electrochemical performance and interface stability of NCMA83 (LiNi_0.83Co_0.06Mn_0.06Al_0.05O₂) cathodes. Compared to conventional combinations with LPSC (Li₆PS₅Cl) solid electrolytes, LATP coatings significantly reduce interfacial reactivity and improve cycling stability. Structural and morphological analyses reveal that LATP coatings maintain the crystallinity of NCMA83 while fine-tuning its lattice stress. Electrochemical testing demonstrates that LATP-modified samples (83L5) achieve superior capacity retention (65 mAh/g after 50 cycles) and reduced impedance (R_ct ~200 Ω), compared to unmodified samples (83L0). These results highlight LATP’s potential as a surface engineering solution to mitigate degradation effects, enhance ionic conductivity, and extend the lifespan of high-capacity SSBs.