BaTaO2N nitrided from a precursor oxide having a perovskite-type structure and a Ba/Ta ratio of unity, nominally expressed as (Na1/4Ba3/4)(Zn1/4Ta3/4)O3, shows an apparent quantum yield of 11.9% at 420 nm during the photocatalytic oxygen evolution reaction. This is more than five times greater than those reported for existing BaTaO2N photocatalysts.
30 November 2018 in Journal of Materials Chemistry A
A series of LaMgxNb1−xO1+3xN2−3x solid solutions (0.0 ≤ x ≤ 0.5) was synthesized in an attempt to modify the band structures and improve the overall water splitting activity of these compounds.