Composting may change the adsorption characteristics and mechanisms of organic materials due to their differences in organic chemical functional groups and surface structures. The adsorption properties of heavy metals onto the municipal solid waste compost (MSW-C) and its secondary fermentation form (MSW-SC) were comparatively investigated in single, binary and multiple solutions by batch experiments. In the single-metal system, the maximum adsorption capacities of Cu, Zn, Cd and Ni onto MSW-SC were 29.2, 26.3, 38.1 and 22.0 mg g−1, respectively, and showed higher than that of MSW-C. The adsorption fitted best with the pseudo-second-order kinetics and Langmuir isotherms. The competitive adsorption results indicated that the composts exhibited good selectivity in the adsorption of Cu over Cd, Zn and Ni; thus, for the quaternary-metal systems, the adsorption sequence was Cu > Zn > Cd > Ni. Humic acid content, cation exchange capacity and surface area were increased following the secondary composting. FTIR analysis indicated amine and aromatic compounds were main binding sites accounting for metal sorption. SEM–EDX analysis suggested that the MSW-SC had rough surfaces and stronger adsorption capacity. Decreasing percentage of exchangeable metals was found in the metal-loaded MSW-SC based on a speciation analysis. This study highlights the interactive impacts of different metals during adsorption by compost with different maturity, the secondary composting process was a multifunctional improvement of sorption characteristics and MSW-SC was developed to be a highly efficient biosorbent.
The existing slope stability research, which is based on the fluid–solid coupling theory, is mainly focused on the slopes of central and eastern China. The impact of rainfall on the stability of the dump slope has often been ignored. It is worthwhile to reveal the mechanism of the fluid–solid coupling mechanics of dump slopes in the arid desertification area of northwest China under the maximum precipitation. The method of combining the seepage mechanics theory with the geomechanics theory was adopted. Darcy’s law and the mass conservation law were introduced to derive and establish the fluid–solid coupling analysis method. Taking the Xinxing Coal Mine in Wuhai City, China, as an example, the finite element software ABAQUS was used to construct the fluid–solid coupling model for slope stability analysis with unsaturated soil. The equivalent rainfall intensity of 68 mm/h for 1 h and 18 mm/h for 24 h was designed in the simulation, respectively. Four different types of initial water content (i.e., 1.72%, 7.34%, 14.69%, and 22.03%) of the dump slopes were defined as the initial conditions. The high-steep slope was compared to the standard slope. Therefore, a set of sixteen rainfall schemes was proposed. The variation regularity of slope stability was thoroughly discussed in regards to four areas: vertical deformation, pore water pressure distribution, equivalent plastic strain, and safety factor. As was expected, the research showed that the slope height and angle have a significant effect on the slope stability. When high-intensity rainfall occurs for a short duration, the slope tends to be more stable as the initial water content increases on the slope. When low-intensity rainfall occurs over a long period, the slope stability reduces if the initial water content is too high or too low in the slope.
Aerobic composting is one of the methods for the resource utilization of submerged plant residues. This study investigated the effects of biochar, wetland sediments and microbial agents added individually or combined on the humification process, lignocellulose degradation and microbial communities during Ceratophyllum demersum and Potamogeton wrightii composting. The results showed that the addition of wetland sediment and biochar was found to significantly elevate the composting temperature and humification of compost products. The average content of lignin in wetland sediment and/or biochar treatments was 12.2–13.5%, which was higher than the control group (10.9–11.45%). Compared with the organic matter (19.4%) and total nitrogen concentration (35.3%) of compost treated with complex microbial agent treatments, the homemade microbial agents significantly increased the values by 22.1% and 41.0%, respectively. By comparing the differences in microbial communities among different treatments, the sediments and homemade agents demonstrated greater increases in activity and diversity of lignocellulose degradation-related microbes, especially for Truepera and Actinomarinale. Humus component and temperature were the most critical parameters influencing the changes in the bacterial community. Based on these results, a combination of biochar and homemade agents was a promising additive for an effective composting strategy, and sediment was identified as a potential control of bacterial diversity in wetland plant compost.