Polyphenol compounds were extracted from Myrtus communis L. berries (Myrtaceae) by maceration in 70% ethanol and analysed by HPLC-DAD and electrospray mass spectrometry. The Myrtus berries were collected at maturity from seven localities on the island of Corsica (France) and the sampling was carried out during three years. The polyphenol composition of Corsican Myrtus berries was characterized by two phenolic acids, four flavanols, three flavonols and five flavonol glycosides. The major compounds were myricetin-3-O-arabinoside and myricetin-3-O-galactoside. Principal components analysis (PCA) is applied to study the chemical composition and variability of myrtle berries alcoholic extracts from the seven localities. Canonical analysis and PCA data distinguishes two groups of myrtle berries characterized by different concentrations of polyphenols according to soil and years of harvest. The variations in the polyphenol concentration were due to biotic and abiotic factors.
The analysis of combustion kinetics in the gas-phase is decisive for wild land fire behavior modeling. However, the use of detailed reaction mechanisms, which involves a large number of species and reactions, is impractical due to large computational time requirements. The present work proposes a five-step chemical kinetic mechanism to simulate the gas phase combustion processes taking place in wildland fires. Both experimental data and data from simulations run using the PSR code from the CHEMKIN-II package with a detailed kinetic mechanism (GDF-kin 3.0) have been used to calibrate and evaluate the global model under typical wild land fire conditions in terms of the inlet mixture composition, equivalence ratio, and range of temperatures.
Research applications of three-dimensional, time-dependent, computational fluid dynamics fire behavior models, such as the Wildland Urban Interface Fire Dynamics Simulator (WFDS)