This investigation suggests the implementation of ZSM-5 activated carbon composite as a prolific adsorbent for the continuous elimination of Pb²⁺ ions from water. Continuous adsorption experiments were performed by varying three parameters such as process flow rate (2-6 mL min^-1), bed height (2-6 cm), and initial concentration (250–750 mg L^-1). The highest loading capacity of the fixed-bed 213.3 mg L^-1 was achieved with optimal values of 2 mL min^-1 of flow rate, bed height of 6 cm, and initial concentration of 750 mg L^-1, respectively. The breakthrough curves and saturation points were found to appear quickly for increasing flow rates and initial concentration and vice versa for bed depth. The lower flow rates with higher bed depths have exhibited optimal performances of the fixed-bed column. The mechanism of adsorption of Pb²⁺ ions was found to be ion exchange with Na⁺ ions from ZMS-5 and pore adsorption onto activated carbon. The breakthrough curves were verified with three well-known mathematical models such as the Adams-Bohart, Thomas, and Yoon-Nelson models. The later models showed the best fit to the column data over the Adams-Bohart model that can be utilized to understand the binding of Pb²⁺ ions onto the composite. Regeneration of ZSM-5/activated carbon was achieved successfully with 0.1 M HCl within 60 min of contact time. The outcomes conclude that ZSM-5 activated carbon composite is a prolific material for the continuous removal of water loaded with Pb²⁺ ions.

The present report presents a green method for the rapid biogenic synthesis of nanoparticles that offers several advantages over the current chemical and physical procedures. It is easy and fast, eco-friendly, and does not involve any precious elements, hazardous chemicals, or harmful solvents. The synthesized ZnO nanoparticles were characterized using different techniques, such as UV-Visible spectroscopy. The surface plasmon resonance confirmed the formation of ZnO nanoparticles at 344 nm, using UV-Visible spectroscopy. The leaf extract acts as a source of phytochemicals and is primarily used for the reduction and then the formation of stable ZnO nanoparticles by the characteristic functional groups of the extract; the synthesized ZnO nanoparticles were identified using FTIR spectroscopy. The crystalline nature of ZnO-NPs was confirmed via powder X-ray diffraction (XRD). Size and morphology were measured via high resolution transmission electron microscopy (HR-TEM) analysis. The stability of the nanoparticles is established using dynamic light scattering (DLS) and thermogravimetric analysis (TGA). The synthesized ZnO nanoparticles have been found to be a good and efficient catalyst for the synthesis of novel 1,2-dihydro quinazoline derivatives under the green method via a one-pot reaction of 2-amino benzophenone, 1,3-diphenyl-1H-pyrazole carbaldehydes, and ammonium acetate. The synthesized compounds (4a–o) were characterized by the ¹H NMR, ¹³C NMR, and HRMS spectra and were further validated for free-radical scavenging activity. The synthesized ZnO nanoparticles exhibited good antioxidant activity.

This study reports the use of hydrophobic ionic liquid (IL) based on D-galactose for the recovery of Ce (III) and Pr (III) ions from solutions. The equilibrium data were obtained by optimization of batch parameters, and various isotherms and kinetic models were utilised to predict the mechanistic process of sequestration of ions. The Arrhenius activation energies are found to be between 540kJ, suggesting the physisorption process of ions onto IL. The present process is understood to be rapid and exothermic in nature according to thermodynamic experiments. The loading capacity was found to be 179.3gL⁻¹ and 141.5gL⁻¹, respectively, for Ce (III) and Pr (III) ions at pH 5 with a contact time of 30min and dose being 0.1gL⁻¹. The higher uptake capacity is attributed to the presence of a highly electronegative fluorine atom in the IL. These results highlight the potential application of IL in the sequestration of Ce (III) and Pr (III) ions from any water sources.