The advancement of sophisticated smart windows exhibiting superior thermoregulation capabilities in both solar spectrum and long-wave infrared range maintains a prominent objective for researchers in this field. In this study, a Janus window is proposed and prepared based on polymer-stabilized liquid–crystal films/thermochromic materials. It can achieve switchable front long-wave infrared emissivity (ε _Front) and solar modulation ability (ΔT _sol) through dynamic flipping, making it suitable for different seasonal energy-saving requirements. Outdoor experiments show that under daytime illumination, the indoor temperature decreases by 8 °C, and the nighttime temperature drops by 5 °C. MATLAB simulation calculations indicate that the daytime cooling power is 93 W m⁻², while the nighttime cooling power reaches 142 W m⁻². Interestingly, by modifying the conductive layer, it can effectively shield electromagnetic radiation (within the X-band frequency range (8.2–12.4) GHz). Energy simulation reveals the substantial superiority of this device in energy savings compared with single-layer polymer-stabilized liquid crystal, poly(N-isopropyl acrylamide), and normal glass when applied in different climate zones. This research presents a compelling opportunity for the development of sophisticated smart windows characterized by exceptional thermoregulation capabilities.

Intelligent soft robots that integrate both structural color and controllable actuation ability have attracted substantial attention for constructing biomimetic systems, biomedical devices, and soft robotics. However, simultaneously endowing single-layer cholesteric liquid crystal elastomer (CLCE) soft actuators with reversible 3D deformability and vivid structural color changes is still challenging. Herein, a multi-responsive (force, heat and light) single-layer 3D deformable soft actuator with vivid structural color-changing ability is realized through the reduced graphene oxide (RGO) deposition-induced Janus structure of the CLCE using a precisely-controlled evaporation method. This single-layer structural color soft actuator can directly transform from a flat shape to a 3D shape through the photothermal effect. The introduction of RGO not only improves the mechanical properties and color saturation of the CLCE, but also endows it with near-infrared (NIR) light responsiveness via the photothermal effect. Moreover, due to the structural gradient resulting from the spontaneous deposition of RGO during the deswelling process, CLCEs show a stacked structure of the helical CLC layer and RGO-dispersed amorphous layer, which are capable of undergoing multiple reversible 3D deformations. The reversible deformations of biomimetic devices such as petal-like films imitating blooming flowers, thin strips imitating plant tendrils, and a cobweb-inspired catching net are achieved to demonstrate applications of this single-layer RGO/CLCE composite film. This work provides a simple strategy for the construction of single-layer 3D deformable soft actuators.