The current syntheses of imines from benzylamines are often performed in organic solvents or under harsh reaction conditions. Clean oxidation of primary benzylamines to imines has been successfully achieved using H₂O₂ in water at room temperature catalyzed by V₂O₅. Among the 10 imine products, 5 of them precipitated from the reaction and led pure products after simple filtration. No organic solvents are needed in the whole process. The yields are good to quantitative. This represents an efficient and green procedure of the synthesis of imines. A similar green oxidation of benzylamines to aromatic aldehydes is also reported. A benzylic anion-involved mechanism is proposed based on the experiments.

Wind turbines and floating platform upsizing are major trends in the current offshore wind development. However, harsh environmental conditions increase the risk of anchor dragging and mooring failure when deploying large offshore floating wind turbines. Therefore, it is necessary to design a mooring system for the specific deployment site. This study aims to perform the mooring system design of a floating offshore wind turbine (FOWT) operated in the South China Sea, which is a combination of the IEA 15 MW wind turbine and UMaine VolturnUS-S floating platform. Hydrodynamic coefficients were calculated based on the potential flow theory, considering the environmental loads in the South China Sea. Additionally, the hydrodynamic coefficients were imported into AQWA to calculate the time-domain mooring tension. The mooring design parameters, such as mooring line length, nominal sizes, and anchor point, were determined using the criterion of anchor uplift, maximum breaking strength, and fatigue life, respectively. The design criterion required that the anchor uplift is not more than the allowable value, the long-term breaking limit of mooring with a 100-year return period should be less than the maximum breaking limit, and the fatigue damage accumulation in 50 years should be safe. The mooring design procedure provides a reference for mooring system design and safe operation of large floating wind turbines in the South China Sea.

The jacket is the most widely-used fixed foundation for offshore wind turbines due to its superior strength and low installation cost in relatively deep waters. Floating crane vessels are commonly used to install jacket foundations. However, the dynamic coupling between the jacket and the floating vessel might generate complex dynamic responses under wave action. The complexity of the multi-body system requires comprehensive time-domain simulations and statistical analysis to obtain reliable results, especially for the evaluation of the operational safety of offshore lift installations of a jacket foundation. In this context, this study performs numerical simulations and statistical analyses to predict the extreme responses and the preliminary allowable sea states for guiding the lowering operation of a jacket using a floating crane vessel. First, ANSYS-AQWA is used to obtain the hydrodynamic coefficients of the vessel in the frequency domain. A nonstationary time-domain simulation of jacket lowering with winches is performed to identify several preliminary critical vertical positions of the jacket from the time series in an irregular wave. The extreme responses of a target probability are evaluated by the extreme distribution model after a large number of steady-state time-domain simulations of the critical vertical positions in irregular waves. The most critical vertical position is determined from three preliminary critical vertical positions by comparing the extreme responses. Eigenvalue analysis and spectrum analysis of the most critical vertical position of the jacket are carried out to find the natural periods of the system and the dynamic coupling characteristics between different components. The influence of wave direction, significant wave height, and spectrum peak period on the dynamic responses are also analyzed in the most critical vertical position. Furthermore, the optimal wave direction is determined as the head sea. Preliminary allowable sea states are derived by comparing the calculated dynamic amplification coefficient with the defined operational criteria.