Atomically thin two-dimensional (2D) metal oxides exhibit unique optical, electrical, magnetic, and chemical properties, rendering them a bright application prospect in high-performance smart devices. Given the large variety of both layered and non-layered 2D metal oxides, the controllable synthesis is the critical prerequisite for enabling the exploration of their great potentials. In this review, recent progress in the synthesis of 2D metal oxides is summarized and categorized. Particularly, a brief overview of categories and crystal structures of 2D metal oxides is firstly introduced, followed by a critical discussion of various synthesis methods regarding the growth mechanisms, advantages, and limitations. Finally, the existing challenges are presented to provide possible future research directions regarding the synthesis of 2D metal oxides. This work can provide useful guidance on developing innovative approaches for producing both 2D layered and non-layered nanostructures and assist with the acceleration of the research of 2D metal oxides.

The adverse effects of NO₂ on the environment and human health promote the development of high-performance gas sensors to address the need for monitoring. Two-dimensional (2D) metal chalcogenides have been considered an emerging group of NO₂-sensitive materials, while incomplete recovery and low long-term stability are the two major hurdles for their practical implementation. The transformation into oxychalcogenides is an effective strategy to alleviate these drawbacks, but usually requires multiple-step synthesis and lacks controllability. Here, we prepare tailorable 2D p-type gallium oxyselenide with the thicknesses of 3-4 nm, through a single-step mechanochemical synthesis that combines the in-situ exfoliation and oxidation of bulk crystals. The optoelectronic NO₂ sensing performances of such 2D gallium oxyselenide with different oxygen contents are investigated at room temperature, in which 2D GaSe_0.58O_0.42 exhibits the largest response magnitude of 82.2% towards 10 ppm NO₂ at the irradiation of UV, with full reversibility, excellent selectivity, and long term stability for at least one month. Such overall performances are significantly improved over those of reported oxygen-incorporated metal chalcogenide-based NO₂ sensors. This work provides a feasible approach to prepare 2D metal oxychalcogenides in a single-step manner and demonstrates their great potential for room-temperature fully reversible gas sensing.

Room temperature (RT) gas sensors based on low-dimensional materials that mainly included three strategies. (1) Nanostructures optimisation; (2) driven by voltage biasing; (3) assisting with light illumination.

Hollow metal‐organic frameworks (MOFs) with careful phase engineering have been considered to be suitable candidates for high‐performance microwave absorbents. However, there has been a lack of direct methods tailored to MOFs in this area. Here, a facile and safe Ni²⁺‐exchange strategy is proposed to synthesize graphite/CoNi alloy hollow porous composites from Ni²⁺ concentration‐dependent etching of Zeolite imidazole frame‐67 (ZIF‐67) MOF and subsequent thermal field regulation. Such a special combination of hollow structure and carefully selected hybrid phase are with optimized impedance matching and electromagnetic attenuation. Especially, the suitable carrier transport model and the rich polarization site enhance the dielectric loss, while more significant hysteresis loss and more natural resonance increase the magnetic loss. As a result, excellent microwave absorbing (MA) performances of both broadband absorption (7.63 GHz) and high‐efficiency loss (‐63.79 dB) are obtained. Moreover, the applicability and practicability of the strategy are demonstrated. This work illustrates the unique advantages of ion‐exchange strategy in structure design, component optimization, and electromagnetic regulation, providing a new reference for the 5G cause and MA field.