Protected cultivation in modern agriculture relies extensively on plastic-originated mulch films, nets, packaging, piping, silage, and various applications. Polyolefins synthesized from petrochemical routes are vastly consumed in plasticulture, wherein PP and PE are the dominant commodity plastics. Imposing substantial impacts on our geosphere and humankind, plastics in soil threaten food security, health, and the environment. Mismanaged plastics are not biodegradable under natural conditions and generate problematic emerging pollutants such as nano-micro plastics. Post-consumed petrochemical plastics from agriculture face many challenges in recycling and reusing due to soil contamination in fulfilling the zero waste hierarchy. Hence, biodegradable polymers from renewable sources for agricultural applications are pragmatic as mitigation. Starch is one of the most abundant biodegradable biopolymers from renewable sources; it also contains tunable thermoplastic properties suitable for diverse applications in agriculture. Functional performances of starch such as physicomechanical, barrier, and surface chemistry may be altered for extended agricultural applications. Furthermore, starch can be a multidimensional additive for plasticulture that can function as a filler, a metaphase component in blends/composites, a plasticizer, an efficient carrier for active delivery of biocides, etc. A substantial fraction of food and agricultural wastes and surpluses of starch sources are underutilized, without harnessing useful resources for agriscience. Hence, this review proposes reliable solutions from starch toward timely implementation of sustainable practices, circular economy, waste remediation, and green chemistry for plasticulture in agriscience

In recent years, the demand for environmental sustainability has caused a great interest in finding novel polymer materials from natural resources that are both biodegradable and eco-friendly. Natural biodegradable polymers can displace the usage of petroleum-based synthetic polymers due to their renewability, low toxicity, low costs, biocompatibility, and biodegradability. The development of novel starch-based bionanocomposites with improved properties has drawn specific attention recently in many applications, including food, agriculture, packaging, environmental remediation, textile, cosmetic, pharmaceutical, and biomedical fields. This paper discusses starch-based nanocomposites, mainly with nanocellulose, chitin nanoparticles, nanoclay, and carbon-based materials, and their applications in the agriculture, packaging, biomedical, and environment fields. This paper also focused on the lifecycle analysis and degradation of various starch-based nanocomposites.

The current trend of using plastic material in the manufacturing of packaging products raises serious environmental concerns due to waste disposal on land and in oceans and other environmental pollution. Natural polymers such as cellulose, starch, chitosan, and protein extracted from renewable resources are extensively explored as alternatives to plastics due to their biodegradability, biocompatibility, nontoxic properties, and abundant availability. The tensile and water vapor barrier properties and the environmental impacts of natural polymers played key roles in determining the eligibility of these materials for packaging applications. The brittle behavior and hydrophilic nature of natural polymers reduced the tensile and water vapor barrier properties. However, the addition of plasticizer, crosslinker, and reinforcement agents substantially improved the mechanical and water vapor resistance properties. The dispersion abilities and strong interfacial adhesion of nanocellulose with natural polymers improved the tensile strength and water vapor barrier properties of natural polymer-based packaging films. The maximum tensile stress of these composite films was about 38 to 200% more than that of films without reinforcement. The water vapor barrier properties of composite films also reduced up to 60% with nanocellulose reinforcement. The strong hydrogen bonding between natural polymer and nanocellulose reduced the polymer chain movement and decreased the percent elongation at break up to 100%. This review aims to present an overview of the mechanical and water vapor barrier properties of natural polymers and their composites along with the life cycle environmental impacts to elucidate their potential for packaging applications.