This study aims to provide an updated survey of the main thermoplastic polymers in order to obtain recyclable materials for various industrial and indoor applications. The synthesis approach significantly impacts the properties of such materials and these properties in turn have a significant impact on their applications. Due to the ideal properties of the thermoplastic polymers such as corrosion resistance, low density or user-friendly design, the production of plastics has increased markedly over the last 60 years, becoming more used than aluminum or other metals. Also, recycling is one of the most important actions currently available to reduce these impacts and represents one of the most dynamic areas in the plastics industry today.
This study aims to provide an updated survey of the main synthesis methods of copper oxide (CuO) nanoparticles in order to obtain tailored nanosystems for various biomedical applications. The synthesis approach significantly impacts the properties of such nanoparticles and these properties in turn have a significant impact on their biomedical applications. Although not widely investigated as an efficient drug delivery system, CuO nanoparticles have great biological properties including effective antimicrobial action against a wide range of pathogens and also drug resistant bacteria. These properties have led to the development of various approaches with direct applications to the biomedical field, such as tailored surfaces with antimicrobial effect, wound dressings and modified textiles. It is also believed that these nanosystems could represent efficient alternatives in the development of smart systems utilized both for the detection of pathogens and for the treatment of infections.
19 April 2019 in Journal of Biomaterials Science, Polymer Edition
This study aims to provide an overview of the main polyhydroxyalkanoates (PHAs) used in medical applications. In this review, it has been demonstrated that the properties of PHAs can be controlled both by varying the concentration of units in the copolymer and the substrate for PHA production. Another way of controlling the mechanical properties of PHAs is varying the 3HV content, such as the case of P(3HB-co-3HV). A higher 3HV content in the structure of this polyester will lead to a lower cristallinity and, therefore, to greater flexibility, strength and elongation at break. PHAs are biocompatible, completely biodegradable, and non-toxic. Considering the state of the art technologies and their ideal properties, PHAs (especially the short-chain-length PHA polymers) can be tailored for specific medical applications, such as surgical suture, scaffolds, grafts and heart valves or drug delivery systems. Nowaday, random copolyesters of 3HB and 4HB (P(3HB-co-4HB)) are used for the development of biodegradable implants loaded with antibiotics for therapeutic treatment of chronic osteomyelitis. It is also believed that these biodegradable materials can be efficient alternatives for reducing the pollution produced by the medical waste consisting of replacing plastic handles, packs, syringes or tubes that are trashed into the homes, clinics and hospitals around the world.
In the last few years, the preservation of cultural heritage has become an important issue globally, due to the fact that artifacts and monuments are continually threatened by degradation. It is thus very important to find adequate consolidators that are capable of saving and maintaining the natural aspect of these objects. This study aims to provide an updated survey of the main nanomaterials used for the conservation and restoration of cultural heritage. In the last few years, besides the classic nanomaterials used in this field, such as metal nanoparticles (copper and silver) and metal oxides (zinc and aluminum), hydroxyapatite and carbonated derivatives, tubular nanomaterials (such as carbon nanotubes) have been used as a potential consolidate material of cultural heritage. Tubular nanomaterials have attracted attention for use in different fields due to their structures, as well as their ability to present multiple walls. These nanotubes have the necessary properties in preserving cultural heritage, such as superior mechanical and elastic strength (even higher than steel), high hydrophobicity (with a contact angle up to 140°), optical properties (high photodegradation protection), large specific surface area (from 50 to 1315 m2/g, depending on the number of walls) for absorption of other nanomaterials and relatively good biocompatibility.
Considering that the large quantity of waste electrical and electronic equipment plastics generated annually causes increasing environmental concerns for their recycling and also for preserving of raw material resources, decreasing of energy consumption, or saving the virgin materials used, the present challenge is considered to be the recovery of individual polymers from waste electrical and electronic equipment. This study aims to provide an update of the main identification methods of waste electrical and electronic equipment such as spectroscopic fingerprinting, thermal study, and sample techniques (like identification code and burning test), and the characteristic values in the case of the different analyses of the polymers commonly used in electrical and electronic equipment. Additionally, the quality of the identification is very important, as, depending on this, new materials with suitable properties can be obtained to be used in different industrial applications. The latest research in the field demonstrated that a complete characterization of individual WEEE (Waste Electric and Electronic Equipment) components is important to obtain information on the chemical and physical properties compared to the original polymers and their compounds. The future directions are heading towards reducing the costs by recycling single polymer plastic waste fractions that can replace virgin plastic at a ratio of almost 1:1.
In this study, multi-walled carbon nanotubes (MWCNTs) were decorated with different types of nanoparticles (NPs) in order to obtain hybrid materials with improved antimicrobial activity. Structural and morphological analysis, such as Fourier transformed infrared spectroscopy, Raman spectroscopy, X-ray diffraction, transmission electron microscopy, environmental scanning electron microscopy/energy-dispersive X-ray spectroscopy and the Brunauer–Emmett–Teller technique were used in order to investigate the decoration of the nanotubes with NPs. Analysis of the decorated nanotubes showed a narrow size distribution of NPs, 7–13 nm for the nanotubes decorated with zinc oxide (ZnO) NPs, 15–33 nm for the nanotubes decorated with silver (Ag) NPs and 20–35 nm for the nanotubes decorated with hydroxyapatite (HAp) NPs, respectively. The dispersion in water of the obtained nanomaterials was improved for all the decorated MWCNTs, as revealed by the relative absorbance variation in time of the water-dispersed nanomaterials. The obtained nanomaterials showed a good antimicrobial activity; however, the presence of the NPs on the surface of MWCNTs improved the nanocomposites’ activity. The presence of ZnO and Ag nanoparticles enhanced the antimicrobial properties of the material, in clinically relevant microbial strains. Our data proves that such composite nanomaterials are efficient antimicrobial agents, suitable for the therapy of severe infection and biofilms.