A method of preparing Ir_xNi/C clusters by polyol reduction using a XC-72R support was proposed. Due to the 2 nm size of the catalyst particles, more active sites are exposed. This is a promising route for the development of efficient water splitting electrocatalysts.

Owning to their distinctive electronic structure, rare-earth-based catalysts exhibit good performance in the oxygen reduction reaction (ORR) and can replace commercial Pt/C. In this study, CeO₂-modified N-doped C-based materials were synthesized using salt template and high-temperature calcination methods, and the synthesis conditions were optimized. The successful synthesis of CeO₂–CN–800 was confirmed through a series of characterization methods and electrochemical tests. The test results show that the material has the peak onset potential of 0.90 V and the half-wave potential of 0.84 V, and has good durability and methanol resistance. The material demonstrates good ORR catalytic performance and can be used in Zn–air batteries. Moreover, it is an excellent catalyst for new energy equipment.

Seeking an efficient, sensitive, and stable catalyst is crucial for no-enzyme glucose sen-sors to detect glucose content accurately. Herein, we constructed a catalyst of selenide cobalt (CoSe₂) on carbon nanomaterials by auxiliary pyrolysis of sodium chloride. The CoSe₂ on carbon nanosheets possesses good selectivity and a wide linear range up to 5 mM. Based on its good detection per-formance, the CoSe₂ nanomaterial is expected to be an emerging catalyst for no-enzyme sensors.

Developing renewable energy sources and controlling water pollution are critical but challenging problems. Urea oxidation (UOR) and methanol oxidation (MOR), both of which have high research value, have the potential to effectively address wastewater pollution and energy crisis problems. A three-dimensional neodymium-dioxide/nickel-selenide-modified nitrogen-doped carbon nanosheet (Nd₂O₃-NiSe-NC) catalyst is prepared in this study by using mixed freeze-drying, salt-template-assisted technology, and high-temperature pyrolysis. The Nd₂O₃-NiSe-NC electrode showed good catalytic activity for MOR (peak current density ~145.04 mA cm⁻² and low oxidation potential ~1.33 V) and UOR (peak current density ~100.68 mA cm⁻² and low oxidation potential ~1.32 V); the catalyst has excellent MOR and UOR characteristics. The electrochemical reaction activity and the electron transfer rate increased because of selenide and carbon doping. Moreover, the synergistic action of neodymium oxide doping, nickel selenide, and the oxygen vacancy generated at the interface can adjust the electronic structure. The doping of rare-earth-metal oxides can also effectively adjust the electronic density of nickel selenide, allowing it to act as a cocatalyst, thus improving the catalytic activity in the UOR and MOR processes. The optimal UOR and MOR properties are achieved by adjusting the catalyst ratio and carbonization temperature. This experiment presents a straightforward synthetic method for creating a new rare-earth-based composite catalyst.

In this study, high temperature pyrolytic carbon materials were used to introduce defect sites. At the same time, the oxygen vacancies on the surface of cerium enhance the adsorption of CO ₂ and enhance the electrocatalytic activity.

Methanol oxidation (MOR) and urea oxidation (UOR) have been considered for new types of fuel cells, but the lack of highly active nonnoble metal catalysts restricts such cells. A NiCo-modified biomass carbon (milk as the carbon source)-based catalyst with a 3D structure is synthesized by using salt templates. The results show that 3D-C-NiCo (1:1) exhibits excellent MOR and UOR properties with a potential of 1.33 V vs. RHE and 1.35 V vs. RHE at 10 mA cm⁻², respectively. MOR and UOR reactions not only can replace the oxygen evolution reaction (OER) in consumption of electrolytic water but also can effectively degrade wastewater pollution rich in methanol and urea.