To study the soil-water effect of red clay, a leaching test is conducted by loading red clay into a soil column and collecting the leaching waste liquid periodically for analysis of the ion content and conductivity changes in the leaching waste liquid. After leaching and filtering, the soil is removed from the column and reconstituted as a straight-shear specimen for a straight-shear test. Ca²⁺, Mg²⁺, and SO₄²⁻ ions increased and then stabilized in water samples as leaching time increased, while Na⁺, Cl⁻, and NO₃⁻ declined and then stabilized. Due to their presence in the leaching solution, Ca²⁺, Mg²⁺, and SO₄²⁻ ions are initially adsorbed by the soil and then saturated by adsorption. In contrast, Na⁺, Cl⁻, and NO₃⁻ precipitate out of the soil due to the dissolution and ion exchange of the soil sample, thereby weakening their effects. Consequently, these ions appear to vary in various ways. The relationship between ion content in solution and conductivity has also been discovere, and the conductivity varies with the total ion charge in the solution. The angle of internal friction decreases as the leaching time increases, but the cohesion of the soil increases.

Engineering practice and real-life cases show that the geological conditions of the Guilin overlying karst site are complex. In particular, the groundwater, which drives the accelerated formation of soil cavities, and the thickness of the overlying soil layer, which affects the speed of the groundwater subsidence process. Therefore, this paper is based on a physical model to evaluate the effects of groundwater level changes caused by different factors on the deformation of karst cover. The model tests are simulated for different cover thicknesses (6 cm, 9 cm, 12 cm, 15 cm, 18 cm) under rainfall and other recharge, cavity supply, and drainage conditions at the same density (1.40 g/cm³) and initial water content (30%), respectively. The results show that with the increase of rainfall and other recharge time, the basic change trend of different cover thicknesses is that the infiltration curve changes faster at the beginning and slows down at the end, but the thicker the cover, the slower the overall deformation; at a certain rate of cavity recharge and drainage, the thicker the cover, the smaller the deformation caused by the fluctuation of groundwater level. The cavity recharge makes the cover displacement obvious, in the order of 0.304 cm, 0.173 cm, 0.118 cm, 0.068 cm, and 0.056 cm. After the formation of the cavity, the rainfall, other recharge, and the cavity supply and drainage accelerate the destruction and deformation of the soil body and the upward development of the cavity. The research results provide theoretical support for the subsequent prevention and control of karst collapse in covered karst areas, and have certain practical engineering significance.

The heavy metal contamination of red clay in Guilin is a serious problem. Lead ions pollute red clay and have a series of effects, which affect the macroscopic properties of red clay. However, fundamentally, the effects occur because the internal microstructure of red clay is eroded by Pb²⁺, which results in the change in the macroscopic properties of red clay. Therefore, we adopted a mercury injection experiment and used electronic microscope Pb²⁺ to explore the microscopic mechanism through which red clay is internally influenced. From the mercury injection experiment, we found that an increase in the concentration of Pb²⁺ increased soil pore diameter and volume, and that a higher heavy metal content of Pb²⁺ had a greater effect on red clay cementation. Using scanning electron microscopy, we found that when the micro-image magnification was 500 and 20,000 times, the inside of the red clay pore increased with the increase in the concentration of Pb²⁺, showing that the heavy metal within the microstructure damaged the red clay. The above two experiments showed that heavy metal ions increase the intergranular fractures of red clay, and the thickness of the double layer reduces, which results in the weakening of the interaction force between particles.