This paper aims to assess experimentally the mechanical and tribological behavior of conventional and functionally graded (FG) polymeric matrix composites reinforced with continuous glass fibers. The small punch test (SPT) and a pin-on-disc device were used in the present work to examine the mechanical and wear behavior, respectively. The hand lay-up technique was used in the present investigation to manufacture the conventional and FG composites. Various wooden looms with different nailed spacing were employed to manufacture the FG composites. According to test type, the FG composite is composed of four and ten layers, with a different glass fiber volume of fraction (V_f%) for each layer. In addition, the finite element simulation based on Hashin’s failure criterion and cohesive zone modeling was used to show the progressive failure and give more explanation regarding the flexural behavior of such composites. The present results indicate that the wear rate of an FG composite could be affected by many factors, including the disk speed, applied load, the composite layers number, and average glass fiber volume fraction. On the other hand, the arrangement of layers in the composite materials by variation of V_f% for each layer can improve the wear rate and value of the ultimate load before the fracture of the composite material when subjected to SPT. The experimental and numerical results for all SPT specimens showed that the fracture of the SPT specimens began beneath the punch tip and grew along the fiber direction. The ultimate flexural capacity of FG composites increased by 30% compared with the conventional composites.

In this study, zinc-oxide (ZnO) nanoparticles (NPs) doped with cobalt (Co) were synthesized using a simple coprecipitation technique. The concentration of Co was varied to investigate its effect on the structural, morphological, optical, and dielectric properties of the NPs. X-ray diffraction (XRD) analysis confirmed the hexagonal wurtzite structure of both undoped and Co-doped ZnO-NPs. Scanning electron microscopy (SEM) was used to examine the morphology of the synthesized NPs, while energy-dispersive X-ray spectroscopy (EDX) was used to verify their purity. The band gap of the NPs was evaluated using UV-visible spectroscopy, which revealed a decrease in the energy gap as the concentration of Co2+ increased in the ZnO matrix. The dielectric constants and AC conductivity of the NPs were measured using an LCR meter. The dielectric constant of the Co-doped ZnO-NPs continuously increased from 4.0 × 10⁻⁹to 2.25 × 10⁻⁸, while the dielectric loss decreased from 4.0 × 10⁻⁸to 1.7 × 10⁻⁷as the Co content increased from 0.01 to 0.07%. The a.c. conductivity also increased with increasing applied frequency. The findings suggest that the synthesized Co-doped ZnO-NPs possess enhanced dielectric properties and reduced energy gap, making them promising candidates for low-frequency devices such as UV photodetectors, optoelectronics, and spintronics applications. The use of a cost-effective and scalable synthesis method, coupled with detailed material characterization, makes this work significant in the field of nanomaterials and device engineering.

The development of cost-effective metal molybdates with enhanced energy storage capabilities has garnered significant attention as promising redox-active electrodes for asymmetric supercapacitors (ASCs). In this work, we synthesized binder-free copper molybdate (CMO) nanostructures on nickel foam using a simple hydrothermal process and thoroughly investigated their structural and electrochemical properties. The resulting CMO nanostructures exhibited a hybrid nanosheet–nanoplate morphology with a layered structure, providing an increased electroactive surface area. The structural integrity and elemental composition were confirmed using X-ray diffraction, X-ray photoelectron and X-ray (EDX) spectroscopy, showing a homogeneous distribution of copper, molybdenum, and oxygen elements. Electrochemical analysis showed that the hydrated CMO (CMO_BH) electrode provides higher specific capacitance and redox behavior than the thermally treated CMO (CMO_AH) electrode. The higher performance is attributed to the superior conductivity of CMO_BH and the presence of hydroxyl groups, which enhance redox-type charge storage. Moreover, the ASC device fabricated using the hydrated CMO_BH and activated carbon electrodes achieved a high operating voltage of 1.6 V with a maximum specific capacitance of 142.1 F g⁻¹ at 1 A g⁻¹, an energy density of 48.6 W h kg⁻¹ and a power density of 12.5 kW kg⁻¹, respectively. Additionally, the device demonstrated excellent cycling stability, retaining 89.1% of its capacitance after 10 000 cycles. The ASCs also successfully powered light-emitting diodes, emphasizing their potential for practical energy storage applications.