Expanding the world of 2D materials: Two-dimensional (2D) materials have a wide variety of potential applications in the electronics industry. However, certain compositions of 2D materials are difficult to obtain owing to the challenges in exfoliating thin sheets from bulk crystals. Zavabeti et al. exploited liquid metals to synthesize 2D Ga 2 O 3 , HfO 2 , Gd 2 O 3 , and Al 2 O 3 . The 2D sheets appear as a surface layer in gallium-based liquid metals after the Hf, Gd, or Al is dissolved into the bulk alloy. The 2D oxide that appears on the surface is the oxide with the lowest energy, suggesting that it should be possible to make other 2D oxides by using the same process. Science , this issue p. 332
A variety of deposition methods for two-dimensional crystals have been demonstrated; however, their wafer-scale deposition remains a challenge. Here we introduce a technique for depositing and patterning of wafer-scale two-dimensional metal chalcogenide compounds by transforming the native interfacial metal oxide layer of low melting point metal precursors (group III and IV) in liquid form. In an oxygen-containing atmosphere, these metals establish an atomically thin oxide layer in a self-limiting reaction. The layer increases the wettability of the liquid metal placed on oxygen-terminated substrates, leaving the thin oxide layer behind. In the case of liquid gallium, the oxide skin attaches exclusively to a substrate and is then sulfurized via a relatively low temperature process. By controlling the surface chemistry of the substrate, we produce large area two-dimensional semiconducting GaS of unit cell thickness (∼1.5 nm). The presented deposition and patterning method offers great commercial potential for wafer-scale processes.
Large-capacity content addressable memory (CAM) is a key element in a wide variety of applications. The inevitable complexities of scaling MOS transistors introduce a major challenge in the realization of such systems. Convergence of disparate technologies, which are compatible with CMOS processing, may allow extension of Moore's Law for a few more years. This paper provides a new approach towards the design and modeling of Memory resistor (Memristor)-based CAM (MCAM) using a combination of memristor MOS devices to form the core of a memory/compare logic cell that forms the building block of the CAM architecture. The non-volatile characteristic and the nanoscale geometry together with compatibility of the memristor with CMOS processing technology increases the packing density, provides for new approaches towards power management through disabling CAM blocks without loss of stored data, reduces power dissipation, and has scope for speed improvement as the technology matures.
17 March 2010 in Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences
In 2008, researchers at the Hewlett–Packard (HP) laboratories published a paper in Nature reporting the development of a new basic circuit element that completes the missing link between charge and flux linkage, which was postulated by Chua in 1971 (Chua 1971 IEEE Trans. Circuit Theory18 , 507–519 ( doi:10.1109/TCT.1971.1083337 )). The HP memristor is based on a nanometre scale TiO 2 thin film, containing a— doped region and an undoped region. Further to proposed applications of memristors in artificial biological systems and non-volatile RAM, they also enable reconfigurable nanoelectronics. Moreover, memristors provide new paradigms in application-specific integrated circuits and field programmable gate arrays. A significant reduction in area with an unprecedented memory capacity and device density are the potential advantages of memristors for integrated circuits. This work reviews the memristor and provides mathematical and SPICE models for memristors. Insight into the memristor device is given via recalling the quasi-static expansion of Maxwell’s equations. We also review Chua’s arguments based on electromagnetic theory.