Agropellets are presented as a suitable product to be produced in certain agro-industries which could become Integrated Biomass Logistic Centres (IBLC) by taking advantage of its current resources during those periods in which their facilities are underused. Wheat straw and maize stalk were selected to be blended with forestry wood in an agro-industry dedicated to animal feed production. The materials were characterized to assess the quality of the input material. Taking into account the former, different pellets (blends of woody and herbaceous biomass) were produced and tested in a fixed bed reactor in order to study their combustion behaviour. Additionally, several predictive indexes were also calculated to assess sintering and deposition occurrence probability. Ash sintering degree was found to be directly related to composition and highly dependent on Si content. Moreover, an increase of the wood content in the blend did not proportionally imply a higher quality of the final blend, as would be expected. Regarding deposition, due to the high number of factors involved in this phenomenon, it has not been possible to draw clear conclusions. To do this, it was necessary to delve into the deposition mechanisms, which is addressed in the second part of this paper. Thus, despite the appearance of sintering and deposition phenomena, the combustion behaviour was satisfactory in the test carried out. Additionally, it has been demonstrated that agro-industries can act as IBLCs, producing blended pellet for the energy market that aligns with the standard ISO 17225-6.

Eight different pellets (one woody and seven blends of woody and herbaceous biomass) produced by an agro-industry were tested in a fixed-bed reactor to characterize their behaviour during their combustion process. The objective was to analyze the possible problems that could arise and, thus, achieve advances in the greater penetration of these agropellets in the energy market. The blends’ design and tests results are presented in the first part of this article. The results of the bottom ash and fly ash samples obtained from the combustion tests using SEM-EDS and P-XRD techniques were analyzed in order to delve into the sintering and deposition phenomena, respectively. Regarding the sintering, a clear relationship has been found between the results of the SEM-EDS analysis and the initial composition of the ash of the fuels. Additionally, the analysis of the results confirms a different ash behaviour regarding the sintering phenomenon depending on the ratio between the amounts of Si, Ca + Mg and K + Na. With respect to deposition, it has been determined that in woody pellets, showing the lower sintering degree, the predominant deposition mechanism is by inertial impact, while in blend pellets it is by condensation, which increases when the percentage of herbaceous in the mixture increases. It has been proved that, in order to compensate (at least partially) for the negative effect of the herbaceous components in the blends, working with a higher λ value is interesting, as it achieves a decrease in the combustion temperature (with λ >1), which implies both a decrease in the sintering degree and in the deposition, improving therefore the ash behaviour in the combustion of agropellets.