The convergence of the close-coupling formalism is studied by expanding the target states in an orthogonal Laguerre basis. The theory is without approximation, and convergence is established by simply increasing the basis size. We present convergent elastic, 2s, and 2p differential cross sections, spin asymmetries, and angular-correlation parameters for the 2p excitation at 35, 54.4, and 100 eV. Integrated and total cross sections as well as T-matrix elements for the first five partial waves are also given.
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We present the convergent close-coupling theory for the calculation of electron-helium scattering. We demonstrate its applicability at a range of projectile energies of 1.5 to 500 eV to scattering from the ground state to n≤3 states. Generally, good agreement with experiment is obtained with the available differential, integrated, ionization, and total cross sections, as well as with the electron-impact coherence parameters up to and including the 3 D-state excitation. This agreement is shown to be overall the best of the currently used electron-helium scattering theories. On occasion, some significant discrepancies with experiment are observed, particularly for the triplet-state excitations.
We extend the convergent-close-coupling method for the calculation of electron-hydrogen scattering to hydrogenlike targets, atoms, or ions. These include H, Li, Na, and K, atoms, as well as the multitude of ions which have the same isoelectronic sequence as any of these atoms. The reliability of the method is independent of the projectile energy, and we demonstrate its applicability by achieving excellent agreement with a large set of measurements for electron scattering on sodium at projectile energies ranging from 1 to 54.4 eV. These measurements include spin asymmetries, singlet and triplet , reduced Stokes parameters, differential, integrated, and total cross sections, as well as the total ionization spin asymmetry. The method is found to give better agreement with experiment than any other over this entire energy range.
30 July 2002 in Journal of Physics B: Atomic, Molecular and Optical Physics
We present the total ionization cross section and spin asymmetry at projectile energies ranging from threshold to 500 eV for electron-impact excitation of atomic hydrogen. They are calculated using the convergent close-coupling formalism of Bray and Stelbovics [Phys. Rev. A 46, 6995 (1992)]. Both observables are found to be in complete quantitative agreement with measurements over almost the entire energy range. This is the only electron-atom scattering theory that is able to achieve this result to date.