Increasing the reliability of combustion engines while further reducing emissions and life cycle costs are the main drivers for optimizing lubricating oil consumption (LOC). However, in order to reduce the lube oil consumption of an engine, it is crucial to measure it accurately. Therefore, a LOC measurement device based on the use of the stable isotope deuterium has been developed. Previous publications have focused on the use of passenger car engines. This publication describes the first application of this newly developed method on a large gas engine. This is of particular interest as large-bore engines might show different oil consumption behavior, much higher LOC in gram per hour and the bigger oil reservoir need larger amounts of tracer. Additionally, a different type of fuel has an effect on oil consumption measurement as well, as presented in this paper. The results showed this method can be applied to large gas engines as well after conducting minor changes to the measurement setup. However, other than liquid fuels, the origin and isotopic composition of the natural gas has to be monitored. Ideally, gas from large storage is used for carrying out these measurements.

Because of the impact of lubrication on the efficiency and the lifecycle cost and emissions, the lubricating-oil consumption (LOC) is one of the key indicators in the research and development of internal combustion engines. State-of-the-art methods for LOC measurement are based on the use of a certain tracer to track the oil consumption. However, all of the currently available tracers have their downsides (e.g., the use of a radioactive tracer, corrosive emissions, etc.). Therefore, in the course of this research project, a new tracer substance that is based on a stable nonradioactive isotope of hydrogen—deuterium—was developed and tested thoroughly. The LOC is monitored by a hydrogen/deuterium isotopic ration in the exhaust gas by using an isotopic water analyzer. Tribologically important properties, such as the viscosity, stability, and compatibility of the tracer were investigated by laboratory experiments by using several tools, such as infrared spectroscopy, gas chromatography, thermogravimetry, etc. The properties relevant to the applicability of the method, such as the accuracy and the reproducibility, were investigated by engine test-bench experiments. Finally, long-term stability tests of the tracer were conducted with a field test.

Lube oil emission is thought to have a negative influence on hydrocarbon and particle emissions, autoignition and the life-cycle cost of internal combustion engines. Thus, one of the major goals of combustion engine research and development is to optimize lube oil consumption, for example by optimizing the tribological behavior of the piston group (interaction between piston rings and cylinder liner). This requires the application of a fast and accurate lube oil consumption measurement method. Methods such as gravimetric and volumetric measurement are outdated for R&D applications because of measurement time, absolute accuracy as well as repeatability, however some OEMs are still applying this method. At present, the use of tracer methods for measuring lube oil consumption is considered the most promising in terms of decreasing measurement time and increasing accuracy. For example, sulfur as a tracer is one of the most established methods for measuring lube oil consumption, but previous publications have revealed downsides and future challenges of its use. This publication, however, highlights the challenges of using the stable hydrogen isotope deuterium as a tracer which are still to overcome, in order to become a viable and reliable method for measuring lube oil consumption on internal combustion engines. In the introduction, a novel concept of measuring lube oil consumption with deuterated engine oil and the test bench setup are explained. Following laboratory experiments, test bench runs on a heavy-duty diesel engine and long-term studies on a field engine, three major challenges facing the new approach are identified and potential solutions are proposed. First, the long-term stability of the tracer in the lube oil and potential changes in the physical and chemical properties of the oil due to deuteration are discussed in light of the results of tests on a field engine that uses deuterated engine oil. Second, the hydrogen-deuterium exchange process to mark the oil with the tracer is examined and potential approaches for reducing cost and duration are highlighted. The universal applicability of the deuteration process to several base oil groups is also explained. Finally, the detection of deuterium in the gas of the engine exhaust and potential cross-sensitivities to trace gases as well as other crucial limitations of the detector in analyzing engine exhaust are addressed. The summary presents the requirements for converting the experiments with a deuterium tracer into a reliable method for lube oil consumption measurement providing crucial properties such as high accuracy, short measurement time, effort and ease of use.

The accurate and precise measurement of lubricating oil consumption is critical for developing environmentally friendly internal combustion engines, particularly hydrogen-fueled internal combustion engines. The deuterium tracer method is based on the addition of poly-deuterated base oil tracers to fully formulated oils for precise, accurate, and fast lubricating oil consumption measurements. Previously performed measurements have shown that the use of poly-deuterated poly-alpha olefins has minimal impact on lubricating oil properties, except for a slight drop in oil viscosity. To further reduce the impact on lubricating oil characteristics, a new base oil for the synthesis of a poly-deuterated tracer is introduced, and its influence on the lubricating oil’s chemical, tribological, and rheological properties is analyzed. Furthermore, the influence of the tracer addition on the preignition tendencies of the fully formulated oil is also examined. Based on the analyses, no relevant changes in the lubricating oil properties, such as viscosity, density, and thermal degradation behavior, can be observed. Additionally, the deuterium tracer does not negatively influence combustion anomalies, thus reducing preignition tendencies. These results establish the method’s compatibility with new-generation engines, especially hydrogen-fueled internal combustion engines.