A novel hexagonal In ₂ O ₃ with high proportion of exposed {104} facets shows superior performance for CO ₂ hydrogenation to CH ₃ OH.

La compounds photoelectron spectra calibration using La 4d _5/2 peak as internal standard is proposed. This is demonstrated by characterizing different La compounds formed after in situ treatments on a nanorod La ₂ O ₃ catalyst.

The direct conversion of carbon dioxide (CO₂) using green hydrogen is a sustainable approach to jet fuel production. However, achieving a high level of performance remains a formidable challenge due to the inertness of CO₂ and its low activity for subsequent C–C bond formation. In this study, we prepared a Na-modified CoFe alloy catalyst using layered double-hydroxide precursors that directly transforms CO₂ to a jet fuel composed of C₈–C₁₆ jet-fuel-range hydrocarbons with very high selectivity. At a temperature of 240°C and pressure of 3 MPa, the catalyst achieves an unprecedentedly high C₈–C₁₆ selectivity of 63.5% with 10.2% CO₂ conversion and a low combined selectivity of less than 22% toward undesired CO and CH₄. Spectroscopic and computational studies show that the promotion of the coupling reaction between the carbon species and inhibition of the undesired CO₂ methanation occur mainly due to the utilization of the CoFe alloy structure and addition of the Na promoter. This study provides a viable technique for the highly selective synthesis of eco-friendly and carbon-neutral jet fuel from CO₂.