Since 2006, with the implementation of a series of national research projects in the field of earthen site conservation, the Chinese theoretical foundation and technological conservation system for the protection of earthen sites in arid environments has gradually formed. However, there are some global problems such as an unclear relationship between characteristics of diseases on sites and their existing environment, unclear deterioration mechanisms under multi-field coupling, immature stability control technology under dynamic loading, the poor suitability of protection process quality assessment equipment, and a lack of systematic research on comprehensive protection synergy mechanisms. On the basis of summarizing the research achievements in the field of earthen site conservation in China for more than 30 years, and a large number of practical experiences in earthen site reinforcement engineering, this paper expounds the multi-field coupling characteristics of earthen site construction technology, the climatic environment, and dynamic loading and protection measure activities, clarifies the main characteristics of the protection of earthen sites in China at present, puts forward the key scientific and technical problems existing in the conservation of earthen sites, constructs a picture of the research on the conservation of earthen sites under the action of multi-field coupling, and discusses the protection projects of earthen sites under different environments. We hope the technological system can provide support for the transformation of earthen site conservation from the rescuing conservation stage to the stage of both rescuing and preventive conservation, and move the foundation of earthen site conservation towards the stage of preventive protection.
Earthen sites in China have great historic, artistic, and scientific values embedded in archaeology, raw materials, and construction techniques. However, high concentrations of salt could potentially cause severe deformation to these earthen sites, and heavy local precipitation can greatly facilitate the process of dissolution and recrystallization of salt. In this study, environment-simulated experiments are conducted to further understand the process and characteristics of this deformation. Deterioration experiments show that soil samples with low salt content are subjected to a variety of deformations, including cracks and collapses as well as basal corrosion on the surface, whereas those containing higher salts show other deformation forms, surface peeling, and basal corrosion. Intriguingly, higher salt concentration leads to relatively smaller soil volume expansion. We conducted more observations and analyses to reveal the underlying mechanism. Results show that high-content salt will clog capillary pores and make pore size smaller and cause concentration and encrustation of salt on the outer surfaces of soil, which, to a certain extent, blocks water absorption of soil under the influence of rain. Therefore, the degree of soil expansion declines, and the types of soil deterioration change. Nevertheless, further work should be done to reveal the contribution of clay minerals on salty soil swelling. Better understanding of the underlying deterioration mechanism can be helpful in designing more specific preservation strategies for these invaluable earthen sites in the near future.
Interpreting the degradation characteristics of waterlogged archaeological wood (WAW) is crucial for the conservation of wooden cultural heritage. Generally, multidisciplinary diagnostic methods, including physical, micromorphological, and chemical approaches, are employed to evaluate the preservation state of WAW. However, primarily focused on the sample level, this methodology limits the understanding of the variability in degradation from a detailed perspective. In this paper, we adopted the in-situ microscale attenuated total reflectance Fourier transform infrared (ATR-FTIR) method to investigate the degradation variability in waterlogged archaeological Masson pine (Pinus massoniana) wood excavated from the ancient Chinese shipwreck Nanhai No. 1. Specifically, spectra of earlywood (EW), latewood (LW), and compression wood (CW) were extracted and combined with chemometrics to achieve rapid classification of their degradation levels. The micromorphological features of wood cell walls in conjunction with the ratios of lignin (A1509) and carbohydrate (A1370) peak areas were used to estimate the degradation levels. Unlike recent wood, moderate degradation in CW and severe degradation in EW and LW were classified in archaeological samples. The degradation levels were effectively determined through principal component analysis (PCA) and sparse partial least squares discriminant analysis (sPLSDA). The results suggest that chemometric analysis is a promising method to discern the variable degradation levels of archaeological wood at the tissue level. The methodologies developed in this study provide detailed insights into the degradation characteristics in WAW and improve the accuracy of evaluating the preservation state.
7 March 2024 in Archaeological and Anthropological Sciences
Natural hydraulic lime (NHL) can be used as an inorganic cementitious material, as it exhibits low shrinkage, salt-alkali resistance, moderate strength, and good durability with cultural relics. There has been increasing interest in NHL, as it is considered an appropriate material for the restoration and reinforcement of architectural cultural relics. In this study, limestone and potassium feldspar were mixed and calcined at different ratios and high temperatures, and artificial hydraulic lime (HL) was produced. According to the X-ray diffraction (XRD) results, the resulting products after high-temperature calcination were mainly composed of calcium oxide, dicalcium silicate (C2S), and dicalcium aluminosilicate (C2AS). As a compromise, when potassium feldspar accounted for 30% of the total mass, HL contains a more suitable air-hardening component and hydraulic component. Scanning electron microscope (SEM) and Energy Dispersive Spectrometer (EDS) analyses show that the phases of calcium carbonate (CaCO3) and hydrated calcium silicate (C-S-H) gradually increased with prolonged curing time for HL. To study the partial mechanical properties and durability of HL, a comparison was made with NHL. The mechanical properties were investigated with the flexural and compressive strengths and shrinkage. The results show that HL has higher strength than NHL, but NHL has smaller shrinkage. Accelerated aging tests indicated that HL and NHL5 led to higher resistance to water immersion, fluctuations in temperature and humidity, sulphate decay, an alkali environment, and frost–thaw action than NHL2. HL has excellent mechanical properties and durability and can be considered a conservation material for stone relics in the future.
17 March 2024 in International Journal of Architectural Heritage
1. Salt weathering prevention and treatment in earthen sites constitute a significant challenge in cultural heritage conservation. Protective structures are erected to counter environmental polluti...